The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
Other experiments led Lavoisier to suspect that the portion of the air
which had united with the tin was different from the portion which had
not combined with that metal. He, therefore, set himself to discover
whether there are different kinds of "airs" in the atmosphere, and, if
there is more than one kind of "air," what is the nature of that "air"
which combines with a metal in the process of calcination. He proposed
to cause a metallic calx (that is, the substance formed by calcining
a metal in the air) to give up the "air" which had been absorbed in
its formation, and to compare this "air" with atmospheric air.
About this time Priestley visited Paris, saw Lavoisier, and told him
of the new "air" he had obtained by heating calcined mercury.
Lavoisier saw the great importance of Priestley's discovery; he
repeated Priestley's experiment, and concluded that the air, or gas,
which he refers to in his Laboratory Journal as "l'air dephlogistique
de M. Priestley" was nothing else than the purest portion of the air
we breathe. He prepared this "air" and burned various substances in
it. Finding that very many of the products of these combustions had
the properties of acids, he gave to the new "air" the name _oxygen_,
which means _the acid-producer_.
At a later time, Lavoisier devised and conducted an experiment which
laid bare the change of composition that happens when mercury is
calcined in the air. He calcined a weighed quantity of mercury for
many days in a measured volume of air, in an apparatus arranged so
that he was able to determine how much of the air disappeared during
the process; he collected and weighed the red solid which formed on
the surface of the heated mercury; finally he heated this red solid to
a high temperature, collected and measured the gas which was given
off, and weighed the mercury which was produced. The sum of the
weights of the mercury and the gas which were produced by heating the
calcined mercury was equal to the weight of the calcined mercury; and
the weight of the gas produced by heating the calcined mercury was
equal to the weight of the portion of the air which had disappeared
during the formation of the calcined mercury. This experiment proved
that the calcination of mercury in the air consists in the combination
of a constituent of the air with the mercury. Fig. XVII. (reduced from
an illustration in Lavoisier's Memoir) represents the apparatus used
by Lavoisier. Mayow's supposition was confirmed.
[Illustration: FIG. XVII.]
Lavoisier made many more experiments on combustion, and proved that in
every case the component of the atmosphere which he had named oxygen
combined with the substance, or with some part of the substance, which
was burned. By these experiments the theory of Phlogiston was
destroyed; and with its destruction, the whole alchemical apparatus of
Principles and Elements, Essences and Qualities, Souls and Spirits,
disappeared.
CHAPTER XII.
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