The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
The fact that there is a very definite connexion between the values of
the atomic weights, and the properties, of the elements, lends some
support to the hypothesis that the substances we call, and are obliged
at present to call, elements, may have been formed from one, or a few,
distinct substances, by some process of progressive change. If the
elements are considered in the order of increasing atomic weights,
from hydrogen, whose atomic weight is taken as unity because it is the
lightest substance known, to uranium, an atom of which is 240 times
heavier than an atom of hydrogen, it is found that the elements fall
into periods, and the properties of those in one period vary from
element to element, in a way which is, broadly and on the whole, like
the variation of the properties of those in other periods. This fact
suggests the supposition--it might be more accurate to say the
speculation--that the elements mark the stable points in a process of
change, which has not proceeded continuously from a very simple
substance to a very complex one, but has repeated itself, with certain
variations, again and again. If such a process has occurred, we might
reasonably expect to find substances exhibiting only minute
differences in their properties, differences so slight as to make it
impossible to assign the substances, definitely and certainly, either
to the class of elements or to that of compounds. We find exactly such
substances among what are called the _rare earths_. There are
earth-like substances which exhibit no differences of chemical
properties, and yet show minute differences in the characters of the
light which they emit when they are raised to a very high
temperature.
The results of analysis by the spectroscope of the light emitted by
certain elements at different temperatures may be reasonably
interpreted by supposing that these elements are separated into
simpler substances by the action on them of very large quantities of
thermal energy. The spectrum of the light emitted by glowing iron
heated by a Bunsen flame (say, at 1200° C. = about 2200° F.) shows a
few lines and flutings; when iron is heated in an electric arc (say,
to 3500° C. = about 6300° F.) the spectrum shows some two thousand
lines; at the higher temperature produced by the electric
spark-discharge, the spectrum shows only a few lines. As a guide to
further investigation, we may provisionally infer from these facts
that iron is changed at very high temperatures into substances simpler
than itself.
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