The Story of Alchemy and the Beginnings of ChemistryMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
The Story of Alchemy and the Beginnings of Chemistry
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Alchemy; Chemistry -- History
Sir Norman Lockyer's study of the spectra of the light from stars has
shown that the light from those stars which are presumably the
hottest, judging by the general character of their spectra, reveals
the presence of a very small number of chemical elements; and that the
number of spectral lines, and, therefore, the number of elements,
increases as we pass from the hottest to cooler stars. At each stage
of the change from the hottest to cooler stars certain substances
disappear and certain other substances take their places. It may be
supposed, as a suggestive hypothesis, that the lowering of stellar
temperature is accompanied by the formation, from simpler forms of
matter, of such elements as iron, calcium, manganese, and other
metals.
In the year 1896, the French chemist Becquerel discovered the fact
that salts of the metal uranium, the atomic weight of which is 240,
and is greater than that of any other element, emit rays which cause
electrified bodies to lose their electric charges, and act on
photographic plates that are wrapped in sheets of black paper, or in
thin sheets of other substances which stop rays of light. The
_radio-activity_ of salts of uranium was proved not to be increased or
diminished when these salts had been shielded for five years from the
action of light by keeping them in leaden boxes. Shortly after
Becquerel's discovery, experiments proved that salts of the rare metal
thorium are radio-active. This discovery was followed by Madame
Curie's demonstration of the fact that certain specimens of
_pitchblende_, a mineral which contains compounds of uranium and of
many other metals, are extremely radio-active, and by the separation
from pitchblende, by Monsieur and Madame Curie, of new substances much
more radio-active than compounds of uranium or of thorium. The new
substances were proved to be compounds chemically very similar to
salts of barium. Their compositions were determined on the supposition
that they were salts of an unknown metal closely allied to barium.
Because of the great radio-activity of the compounds, the hypothetical
metal of them was named _Radium_. At a later time, radium was isolated
by Madame Curie. It is described by her as a white, hard, metal-like
solid, which reacts with water at the ordinary temperature, as barium
does.
Since the discovery of radium compounds, many radio-active substances
have been isolated. Only exceedingly minute quantities of any of them
have been obtained. The quantities of substances used in experiments
on radio-activity are so small that they escape the ordinary methods
of measurement, and are scarcely amenable to the ordinary processes of
the chemical laboratory. Fortunately, radio-activity can be detected
and measured by electrical methods of extraordinary fineness, methods
the delicacy of which very much more exceeds that of spectroscopic
methods than the sensitiveness of these surpasses that of ordinary
chemical analysis.
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