One of the earliest notable uses of the electric furnace in a
large electro-chemical industry was for the production of
carborundum, a carbide of silicon, which is remarkably useful as
an abrasive, being available in the manufacture of grinding stones
and other like purposes to replace emery and corundum. It is
produced by the use of a simple electric furnace of the resistance
type, where coke, sand, and sawdust are heated to a temperature of
between 2000 degrees and 3000 degrees C. The chemical reaction
involves the production of carbon monoxide, and gives a carbide of
silicon, a crystalline solid which has the excellent abrasive
properties mentioned. The manufacture was first started by its
inventor, E. G. Acheson, about 1891 on a small scale, and in the
following year 1,000 pounds of the material were produced at the
Niagara Falls works. Within fifteen years its output had increased
to well over six million pounds.
The electric furnaces at Niagara Falls have supplied many
interesting electro-chemical processes. After making a carbide in
the electric furnace it was found possible to decompose it by
further increasing the heat to a point where the second element is
volatilized and the pure carbon in the form of artificial graphite
remains. In more recent work the carbide containing the silicon
has been done away with and ordinary anthracite coal used as a
charge from which the pure graphite is obtained. This graphite has
been found especially useful in electrical work as for electrodes,
while a more recent process enables a soft variety of graphite to
be obtained which becomes a competitor of the natural material.
One of the most interesting of the many electro-chemical processes
is the heating of lime and coke in the electric furnace so as to
obtain a product in the form of calcium carbide, which, on
solution in water, forms acetylene gas, a useful and valuable
illuminant. This process dates from 1893 when T. L. Willson in the
United States first started its manufacture on a large scale, and
the great electrochemist, Henri Moissin, about the same time
independently invented a similar process as a result of his
notable work with the electric furnace. The process involves
merely a transformation at a high temperature, a portion of the
carbon in the form of coke, uniting with pulverized lime to give
the calcium carbide or CaC2. Now this material, when water is
added to it, decomposes, and acetylene or C2H2 is formed, which is
a gas of high illuminating value as the carbon separates and glows
brightly after being heated to incandescence in the flame.
Public-domain text, read in full here on John Shaqi.
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