The electric furnace at Niagara Falls has been able to produce
still another combination in the form of siloxicon by heating
carbon and silicon to a temperature slightly below that required
to produce carborundum. This product is a highly refractory
material and is valuable for the manufacture of crucibles,
muffles, bricks, etc., for work where extreme temperatures are
employed. The electric furnace enables various elements to be
isolated, such. as silicon, sodium, and phosphorus, and when
obtained in their pure state they find wide application.
The most important electro-chemical work of the future is to
devise some means of obtaining nitrogen from the air. It is stated
by scientists that the nitrogen of the soil is being exhausted and
that at some future time the Earth may not be able to bear crops
sufficient for the sustenance of man, unless some artificial means
be found to replenish the nitrogen. Unlimited supplies of nitrogen
exist in the air, but to fix it with other materials in such form
that it will be useful as a fertilizer has been one of the
problems to which the electro-chemists have recently devoted much
attention. By the use of the electric arc and passing air through
a furnace, various substances have been tried to take up the
nitrogen of the air. Thus when calcium carbide is heated and
brought into contact with nitrogen one atom of carbon is given up
and two atoms of nitrogen take its place, resulting in the
production of cyanamide.
Other important electro-chemical processes are involved in the
electrolysis of the various alkaline salts to obtain metallic
sodium and such products as chlorates. Thus by the electrolysis of
sodium chloride metallic sodium and chlorine is obtained. From the
metallic sodium solid caustic soda is then derived by a secondary
reaction, while the chlorine is combined with lime to form
chloride of lime or bleaching powder. In some processes the
electrolysis affords directly an alkaline hypochlorite or a
chlorate, the former being of wide commercial use as a bleaching
agent in textile works and in the paper industry. The same process
employed in the electrolysis of sodium salts is used in the case
of magnesium and calcium.
Electrolysis is also made use of in the manufacture of chloroform
and iodoform, as the chlorine or iodine which is produced in the
electrolytic cell is allowed to act upon the alcohol or acetone
under such conditions that chloroform or iodoform is produced.
Public-domain text, read in full here on John Shaqi.
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