Numerous voltaic combinations and varieties of cell have been
found out. In general, where-ever two metals in contact are placed
in a liquid which acts with more chemical energy on one than on
the other, as sulphuric acid does on zinc in preference to copper,
there is a development of electricity. Readers may have seen how
an iron fence post corrodes at its junction with the lead that
fixes it in the stone. This decay is owing to the wet forming a
voltaic couple with the two dissimilar metals and rusting the
iron. In the following list of materials, when any two in contact
are plunged in dilute acid, that which is higher in the order
becomes the positive plate or negative pole to that which is
lower:--
POSITIVE Iron Silver
Zinc Nickel Gold
Cadmium Bismuth Platinum
Tin Antimony Graphite
Lead Copper NEGATIVE
There being no chemical union between the hydrogen and copper in
the zinc and copper couple, that gas accumulates on the surface of
the copper plate, or is liberated in bubbles. Now, hydrogen is
positive compared with copper, hence they tend to oppose each
other in the combination. The hydrogen diminishes the value of the
copper, the current grows weaker, and the cell is said to
"polarise." It follows that a simple water cell is not a good
arrangement for the supply of a steady current.
The Daniell cell is one of the best, and gives a very constant
current. In this battery the copper plate is surrounded by a
solution of sulphate of copper (Cu SO4), which the hydrogen
decomposes, forming sulphuric acid (H2SO4), thus taking itself out
of the way, and leaving pure copper (Cu) to be deposited as a
fresh surface on the copper plate. A further improvement is made
in the cell by surrounding the zinc plate with a solution of
sulphate of zinc (Zn SO4), which is a good conductor. Now, when
the oxide of zinc is formed by the oxygen uniting with the zinc,
the free sulphuric acid combines with it, forming more sulphate of
zinc, and maintaining the CONDUCTIVITY of the cell. It is only
necessary to keep up the supply of zinc, water, and sulphate of
copper to procure a steady current of electricity.
The Daniell cell is constructed in various ways. In the earlier
models the two plates with their solutions were separated by a
porous jar or partition, which allowed the solutions to meet
without mixing, and the current to pass. Sawdust moistened with
the solutions is sometimes used for this porous separator, for
instance, on board ships for laying submarine cables, where the
rolling of the waves would blend the liquids.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account