The deposition of a metal from a solution of its salt is very
easily shown in the case of copper. In fact, we have already seen
that in the Daniell cell the current decomposes a solution of
sulphate of copper and deposits the pure metal on the copper
plate. If we simply make a solution of blue vitriol in a glass
beaker and dip the wires from a voltaic cell into it, we shall
find the wire from the negative pole become freshly coated with
particles of new copper. The sulphate has been broken up, and the
liberated metal, being positive, gathers on the negative
electrode. Moreover, if we examine the positive electrode we shall
find it slightly eaten away, because the sulphuric acid set free
from the sulphate has combined with the particles of that wire to
make new sulphate. Thus the copper is deposited on one electrode,
namely, the cathode, by which the current leaves the bath, and at
the expense of the other electrode, that is to say, the anode, by
which the current enters the bath.
The fact that the weight of metal deposited in this way from its
salts is proportional to the current, has been utilised for
measuring the strength of currents with a fine degree of accuracy.
If, for example, the tubes of the voltameter described on page 38
were graduated, the volume of gas evolved would be a measure of
the current. Usually, however, it is the weight of silver or
copper deposited from their salts in a certain time which gives
the current in amperes.
Electro-plating is the principal application of this chemical
process. In 1805 Brugnatelli took a silver medal and coated it
with gold by making it the cathode in a solution of a salt of
gold, and using a plate of gold for the anode. The shops of our
jewellers are now bright with teapots, salt cellars, spoons, and
other articles of the table made of inferior metals, but
beautified and preserved from rust in this way.
Figure 44 illustrates an electro-plating bath in which a number of
spoons are being plated. A portion of the vat V is cut away to
show the interior, which contains a solution S of the double
cyanide of gold and potassium when gold is to be laid, and the
double cyanide of silver and potassium when silver is to be
deposited. The electrodes are hung from metal rods, the anode A
being a plate of gold or silver G, as the case may be, and the
cathode C the spoons in question. When the current of the battery
or dynamo passes through the bath from the anode to the cathode,
gold or silver is deposited on the spoons, and the bath
recuperates its strength by consuming the gold or silver plate.
Public-domain text, read in full here on John Shaqi.
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