Chemical and Mechanical Deposits.— A distinction has been made by geologists between deposits of a mechanical, and those of a chemical, origin. By the name mechanical are designated beds of mud, sand, or pebbles produced by the action of running water, also accumulations of stones and scoriæ thrown out by a volcano, which have fallen into their present place by the force of gravitation. But the matter which forms a chemical deposit has not been mechanically suspended in water, but in a state of solution until separated by chemical action. In this manner carbonate of lime is occasionally precipitated upon the bottom of lakes in a solid form, as may be well seen in many parts of Italy, where mineral springs abound, and where the calcareous stone, called travertin, is deposited. In these springs the lime is usually held in solution by an excess of carbonic acid, or by heat if it be a hot spring, until the water, on issuing from the earth, cools or loses part of its acid. The calcareous matter then falls down in a solid state, incrusting shells, fragments of wood and leaves, and binding them together. That similar travertin is formed at some points in the bed of the sea where calcareous springs issue cannot be doubted, but as a general rule the quantity of lime, according to Bischoff, spread through the waters of the ocean is very small, the free carbonic acid gas in the same waters being five times as much as is necessary to keep the lime in a fluid state. Carbonate of lime, therefore, can rarely be precipitated at the bottom of the sea by chemical action alone, but must be produced by vital agency as in the case of coral reefs. In such reefs, large masses of limestone are formed by the stony skeletons of zoophytes; and these, together with shells, become cemented together by carbonate of lime, part of which is probably furnished to the sea-water by the decomposition of dead corals. Even shells, of which the animals are still living on these reefs, are very commonly found to be incrusted over with a hard coating of limestone. If sand and pebbles are carried by a river into the sea, and these are bound together immediately by carbonate of lime, the deposit may be described as of a mixed origin, partly chemical, and partly mechanical. Now, the remarks already made in Chapter II, on the original horizontality of strata are strictly applicable to mechanical deposits, and only partially to those of a mixed nature. Such as are purely chemical may be formed on a very steep slope, or may even incrust the vertical walls of a fissure, and be of equal thickness throughout; but such deposits are of small extent, and for the most part confined to vein-stones.