The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
_=376. Electroplating=_ is the name given to the process of coating
substances with metal with the aid of the electric current. The copper
sulphate, CuSO_{4}, is broken up into Cu and SO_{4} by the current. The
Cu goes to the cathode, and the SO_{4} attacks the anode, gradually
dissolving it if it be copper; that is, the _metal_ part of CuSO_{4} is
carried in the direction of the current.
Most metals are coated with copper before they are silver or gold
plated. A solution of silver is used for silver plating, silver being
used as the anode.
=EXPERIMENT 150. To study the chemistry of electroplating.=
_Apparatus._ Same as in last experiment, but use two carbon
rods for the electrodes. Arrange as in Fig. 114, with the Cu
replaced by another carbon. Two simple cells (§ 275) are also
needed.
=377. Directions.= (A) Allow the current to pass as before. Is
copper still deposited? Does anything occur now at the surface
of the anode? Is the copper deposited as rapidly as before?
(B) Try the effect of the two simple cells joined in series,
Instead of the two-fluid cell.
(C) After a fair coating of copper has been deposited upon the
carbon cathode, reverse the direction of the current through
the copper solution; that is, use the coated rod for the anode.
Allow the current to pass until a change takes place in the
anode.
_=378. Discussion.=_ Ions are the names given to the parts into which
an electrolyte is decomposed by the electric current. In the case of
CuSO_{4}, the ions are Cu and SO_{4}, which is called an acid radical.
This SO_{4} can not dissolve carbon or platinum, so these are used
when water is to be electrolyzed. Where copper is used as the anode
for copper plating, the SO_{4} attacks it, forming CuSO_{4} again,
and this keeps the solution strong. If carbon were used instead, the
SO_{4} would take H_{2} from the water around the anode and H_{2}SO_{4}
(sulphuric acid) would be formed, the oxygen of the water being set
free at the anode. The amount of Cu dissolved from the copper anode
equals nearly the amount deposited upon the cathode. Exp. 150 shows
that the metal is carried in the direction of the current. As hydrogen
is produced at the cathode it is chemically considered a metal.
Public-domain text, read in full here on John Shaqi.
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