The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
_=372. Composition of Water.=_ The two gases liberated in Exp. 147 were
hydrogen (H) and oxygen (O). The chemical formula for water is H_{2}O,
which means that it is composed of two parts, by volume, of H and one
part of O. With proper apparatus these gases may be collected, tested,
and the amounts measured.
_=373. Electromotive Force of Polarization.=_
We know that H and O have a strong chemical attraction, or affinity,
for each other. In order, then, for the current to decompose water,
this attraction between the gases must be overcome; and as soon as the
current ceases, these gases try to rush together again to form water.
This sets up an electromotive force of almost 1.5 volts; in fact, a
current is produced if the H and O be allowed to form water again (See
Storage Cells). To decompose water the current must have an E. M. F. of
over 1.5 volts to overcome this E. M. F. of polarization. It was seen
in the study of simple cells that the current became rapidly weaker
as hydrogen was deposited upon the copper plate, on account of this
opposing electromotive force.
In decomposing other compounds, the anode is made of the metal which
is to be deposited at the cathode. If copper is to be deposited from a
solution of copper sulphate the anode should be a copper plate; this
keeps the solution at same strength, and avoids the opposing E. M. F.
of polarization; that is, a very weak current will do the work (See
Exp. 149), because the electrodes are of the same metal.
=EXPERIMENT 148. To coat iron with copper.=
_Apparatus._ Iron nail, solution of copper sulphate (§ 283).
=374. Directions.= (A) Clean the nail with sandpaper, then hold
it in the copper solution for a few seconds. Machinists often
cover iron or steel tools with a thin coating of copper in this
way.
[Illustration: Fig. 114.]
=EXPERIMENT 149. To study the electrolysis of a solution of
copper sulphate.=
_Apparatus._ Galvanoscope, G V; two-fluid cell, 2-F C; a
tumbler, T, containing about an inch of copper sulphate
solution (§ 283); a wooden cross-piece to which is fastened a
copper strip; carbon rod, C; wire 2 is held to C by a rubber
band. _Arrange_ as in Fig. 114, so that Cu will be the _anode_
(§ 370), the current passing as shown by arrow. A dry cell may
be used for short experiments instead of the 2-F C.
=375. Directions.= (A) The carbon being clean, allow the
current to pass, C and Cu being kept about 1/2 in. apart. Watch
the surface of C, and note the beautiful color of the deposited
copper. Save the coated rod for the next experiment. Has the Cu
plate been acted upon?
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account