The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
The zinc sulphate produced weakens the effect of the acid; in
fact, the acid has to be renewed occasionally, as it is changed
to the sulphate which remains in solution.
=271. Action in Cell Using Impure Zinc.= The above action
takes place in the cell when impure zinc is used, even when no
current passes, heat being produced by the reaction instead of
useful electricity. (See Local Currents.)
=Action in Cell Using Pure Zinc.= When pure zinc (or impure
zinc that has been properly amalgamated) is used in the cell,
it dissolves, or is eaten away, only when the current passes.
It should be noted that the bubbles of hydrogen do not even
then appear at the zinc; they are not seen throughout the body
of the liquid. There seems to be an unseen transfer of hydrogen
from the zinc, through the liquid, to the copper (or other -
plate used), and it appears there in the shape of bubbles. The
larger the quantity of pure zinc dissolved, the stronger the
current, and the larger the amount of hydrogen produced.
As the zinc dissolves it parts with its latent energy, and this
energy forces the electric current through the circuit. While
the hydrogen of the decomposed acid makes its way towards the -
plate, the SO_4 part of it travels towards the Zn plate, where
the ZNSO_4 is formed. (See § 270.)
=EXPERIMENT 111. To see what is meant by "local currents" in
the cell.=
_Apparatus._ Tumbler of dilute sulphuric acid. (§ 258); strip
of unamalgamated zinc; crystal of copper sulphate (blue
vitriol) (No. 86); a galvanized iron nail (No. 69), this being
iron covered with zinc.
=272. Directions.= (A) Hold the nail in the acid for a few
seconds, and note result.
(B) Rub the copper sulphate upon the zinc simply in one spot,
then place the zinc in the acid, noting the result at the spot.
_=273. Local action; Local Currents.=_ Ordinary commercial zinc
contains such impurities as carbon, iron, lead, etc., in small
quantities. It was seen, Exp. 109, that when different metals were in
contact with the zinc, the zinc was rapidly dissolved by the acid. The
impurities in the zinc act like the copper plate in the simple cell,
thus producing _local currents_ in the zinc, which rapidly destroy it
without doing any good. These currents pass from zinc to impurities,
and back to the zinc, without going out into the main wire. This local
action takes place even when the main circuit is open.
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