The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
_=274. Reasons for Amalgamating Zinc Plates.=_ Pure zinc is not
affected by dilute sulphuric acid, but it is too expensive to use in
cells; so amalgamated zinc is used instead, because it is cheaper, and
acts the same as pure zinc. The impurities are removed from the surface
of the zinc, as the zinc alone is dissolved by the mercury. There is,
then, a liquid layer of pure zinc with mercury upon the surface of
the amalgamated plate. This is not acted upon by the acid when the
circuit is open. A stronger and more regular current is produced with
amalgamated zinc than with the impure unamalgamated zinc.
=EXPERIMENT 112. To study the "single-fluid" Galvanic cell.=
_Apparatus._ The galvanoscope G V (No. 58), (See § 240, etc.);
the simple cell arranged as described in § 275, the zinc being
amalgamated.
=275. The Simple Cell= should be arranged so that the plates
will be held firmly in position. The zinc, Zn (No. 60),
and copper, Cu (No. 67), should be fastened to the wooden
cross-piece, W C P (No. 70), as shown in Fig. 85. Care should
be taken not to use longer screws than those provided for (No.
72). If the screws touch each other they will short circuit the
cell. Partly fill the tumbler (No. 65) with dilute sulphuric
acid (§ 258), join wires with connectors to the plates. The
free ends of the wires are then ready to join to apparatus. The
ends of wires _may_ be fastened under the screw-heads instead
of using connectors on the plates. Do not put the plates into
the acid until you read the "directions."
=276. Directions.= (A) Arrange as in Fig. 86. Place the coil
of G V, N and S (§ 244). _Before_ putting the plates in
the acid join them to the 15-turn coil of G V (§ 242). The
compass-needle should point to zero. See that the needle swings
freely.
(B) Place the plates in the acid, and _quickly_ bring the
needle to rest with the aid of the hand, so that you can take
the reading at once before the hydrogen bubbles entirely
cover the copper plate. Watch the action of the needle for a
few minutes. Make a note of the reading, in degrees, at the
beginning of the experiment and at the end of five minutes.
(See Note.)
[Illustration: Fig. 85.]
[Illustration: Fig. 86.]
=Note.= If no change takes place in the position of the needle,
the change beginning inside of 10 seconds after the plates are
let down into the acid, withdraw the plates, then clean and
thoroughly dry the copper to remove all traces of hydrogen.
This may be done by heating the copper over a gas flame. Let
the copper remain in the air 15 minutes, then try again. In
taking the first reading you must work quickly. Catch the
needle during its _first_ swing. If you allow it to swing back
and forth until it comes to rest, your first reading will not
be what it should be.
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