The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made ApparatusSt. John, Thomas M. (Thomas Matthew)
Science
The Study of Elementary Electricity and Magnetism by Experiment: Containing Two Hundred Experiments Performed with Simple, Home-made Apparatus
(C) After the needle has remained in one position, without
change, for 2 or 3 minutes, take hold of the wooden
cross-piece, move the plates back and forth in the acid to
dislodge the hydrogen bubbles, and note carefully the action of
the needle. Does the current seem stronger when the plates are
moved? Can you get the needle back to the first reading?
(D) Remove the plates from the acid, dry and clean the copper,
let them stand in the air for 15 minutes, then take another
quick reading and compare it with the first.
_=278. Polarization of Cells.=_ The acid gets a little weaker, of
course, as it is decomposed by the zinc (§ 270), but the chief cause of
the weakening of the current is hydrogen, which forms a filmy coating
upon the copper plate. This coating even seems to soak into the copper,
and it takes some time for it to be thoroughly removed. The zinc plate
is kept comparatively free from hydrogen by amalgamation.
_=279. Effects of Polarization.=_ The hydrogen bubbles weaken the
current in at least two ways. In the _first_ place, hydrogen is not a
conductor of electricity; so it holds the current back, as any other
resistance would.
_Secondly_, acid acts upon hydrogen as it would upon another metal.
When the copper plate becomes well covered with hydrogen, the acid
cannot touch it; so we really have a _hydrogen plate_ in the cell.
Hydrogen acts very much like zinc in the acid; we say that it is more
electro-positive than copper. The result is, then, that a new current
starts up, and as this is towards the zinc, in the acid, it partially
destroys or neutralizes the main zinc-to-copper current. Practical use
is made of the principles of polarization (see Secondary Batteries).
_=280. Remedies for Polarization; Depolarizers.=_ Any scheme by which
the hydrogen may be destroyed and kept from the inactive, or negative
plate, will prevent polarization. _Mechanical_ means have been employed
to brush away the hydrogen by keeping up a constant circulation of
the liquid. _Chemical action_ is another means by which the hydrogen
may be side-tracked before it gets to the - plate in single-fluid
cells. Substances like nitric acid and bichromate of potash, called
_depolarizers_, contain large quantities of oxygen, and, during
the chemical changes that take place, this oxygen unites with the
hydrogen. These substances are used in zinc-carbon cells. (See § 286,
etc. for various forms of cells.)
There is another form of cell, the _two-fluid_ type, in which
_electro-chemical_ means are employed, and in which a metal is
deposited upon the - plate instead of hydrogen. The - plate is usually
copper, copper being deposited upon it.
=EXPERIMENT 113. To study the "two-fluid" Galvanic cell.=
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