Heat, whether of a gas, a liquid or a solid, is merely the energy of
motion of individual molecules. When we heat up the air of a room
we simply make its molecules move faster, and the total heat of the
substance is the total energy of all the molecules of which it is
composed. In pumping up a bicycle tyre, we drive the piston of the
pump forward in opposition to the impact of innumerable millions of
molecules of air inside the pump. In kicking the opposing molecules out
of its way, the piston increases their speed of motion. The resulting
increase in the energy of motion of the molecules is simply an increase
of heat. We could verify this by inserting a thermometer, or, still
more simply, by putting our hand on the pump; it feels hot.
The molecules of a solid are not possessed of much energy, and so do
not move very fast—so slowly indeed that they seldom change their
relative positions, the neighbouring molecules gripping them so firmly
that their feeble energy of motion cannot extricate them. If we warm
the solid up, the molecules acquire more energy, and so begin to move
faster. After a time they are moving with such speeds that they can
laugh at the restraining pulls from their neighbours; each molecule has
enough energy of motion to go where it pleases, and we have a crowd
of molecules moving freely as independent units, jostling one another
and pushing their way past one another; the substance has assumed the
liquid state. To make the picture definite, ice has melted and become
water; the frozen grip is relaxed, and the molecules flow freely past
one another. Each still exerts forces on its neighbours, but these
are no longer strong enough to preclude all motion. Heat the liquid
further, thus further increasing the energy of motion of the molecules,
and these begin to break loose entirely from their bonds and fly about
freely in space forming a gas or vapour. If we go on supplying heat,
the whole substance will in time assume the gaseous state. Heating the
gas still further merely causes the molecule-bullets to fly faster; it
increases their energy of motion.
Public-domain text, read in full here on John Shaqi.
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