The average energy of motion of the molecules in a gas is proportional
to the temperature of the gas—indeed, this is the way in which
temperature is defined. The temperature must not, however, be measured
on the Fahrenheit or Centigrade scale in ordinary use, but on what is
called the “absolute” scale, which has its zero at -273° Centigrade, or
-469° Fahrenheit. This “absolute” zero, being the temperature of a body
which has no further heat to lose, is the lowest temperature possible.
We can approach to within about one degree of it in the laboratory, and
find that it freezes air, hydrogen and even helium, the most refractory
gas of all, solid. A thermometer placed out in interstellar space, far
from any star, would probably shew a temperature of only about four
degrees above absolute zero, while still lower temperatures must be
reached out beyond the limits of the galactic system.
MOLECULAR COLLISIONS. We may now try to picture a collision between
two molecule-bullets in a gas. Lead bullets colliding on a battlefield
would probably change most of their energy of motion into heat-energy;
they would become hotter, or perchance even melt. But how can the
molecule-bullets transform their energy of motion into heat-energy?
For them heat and energy of motion are not two different forms of
energy, they are one and the same thing; their heat is their energy
of motion. The total energy must be conserved, and there is no
new disguise that it can assume. So it comes about that when two
molecule-bullets collide, the most that can happen is that they may
exchange a certain amount of energy of motion. If their energies of
motion before collision were, say, 7 and 5 respectively, their energies
after collision may be 6 and 6, or 8 and 4, or 9 and 3, or any other
combination which adds up to 12.
It is the same at every collision; energy can neither be lost nor
transformed, and so the bullets on the molecular battlefield go on
flying for ever, happily hitting only one another, and doing no harm
to one another when they hit. Their energies of motion go up and down,
down and up, according as they make lucky hits or the reverse, but the
most they have to fear are fluctuations and never total loss of energy;
their motion is perpetual.
ATOMS
In the gaseous state, each separate molecule retains all the chemical
properties of the solid or liquid substance from which it originated;
molecules of steam, for instance, moisten salt or sugar, or combine
with thirsty substances such as unslaked lime or potassium chloride,
just as water does.
Is it possible to break up the molecules still further? Lucretius
and his predecessors would, of course, have said: “No.” A simple
experiment, which, however, was quite beyond their range, will speedily
shew that they were wrong.
Public-domain text, read in full here on John Shaqi.
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