CAVITY-RADIATION. A crucial case of failure was provided by what is
known as “cavity-radiation.” A body with a cavity in its interior
is heated up to incandescence; no notice is taken of the light and
heat emitted by its outer surface, but the light imprisoned in the
internal cavity is let out through a small window and analysed into
its constituent colours by a spectroscope or diffraction grating. It
is this radiation that is known as “cavity-radiation.” It represents
the most complete form of radiation possible, radiation from which
no colour is missing, and in which every colour figures at its full
strength. No known substance ever emits quite such complete radiation
from its surface, although many approximate to doing so. We speak of
such bodies as “full radiators.”
The nineteenth-century laws of electromagnetism predicted that the
whole of the radiation emitted by a full radiator or from a cavity
ought to be found at or beyond the extreme violet end of the spectrum,
independently of the precise temperature to which the body had been
heated. In actual fact the radiation is usually found piled up at
exactly the opposite end of the spectrum, and in no case does it ever
conform to the predictions of the nineteenth-century laws, or even
begin to think of doing so.
In the year 1900, Professor Planck of Berlin discovered experimentally
the law by which “cavity-radiation” is distributed among the different
colours of the spectrum. He further shewed how his newly discovered law
could be deduced theoretically from a system of electromagnetic laws
which differed very sensationally from those then in vogue.
Planck imagined all kinds of radiation to be emitted by systems of
vibrators which emitted light when excited, much as tuning forks emit
sound when they are struck. The old electrodynamical laws predicted
that each vibration should gradually come to rest and then stop, as
the vibrations of a tuning fork do, until the vibrator was in some way
excited again. Rejecting all this, Planck supposed that a vibrator
could change its energy by sudden jerks, and in no other way; it might
have one, two, three, four or any other integral number of units of
energy, but no intermediate fractional numbers, so that gradual changes
of energy were rendered impossible. The vibrator, so to speak, kept
no small change, and could only pay out its energy a shilling at a
time until it had none left. Not only so, but it refused to receive
small change, although it was prepared to accept complete shillings.
This concept, sensational, revolutionary and even ridiculous, as many
thought it at the time, was found to lead exactly to the distribution
of colours actually observed in cavity-radiation.
Public-domain text, read in full here on John Shaqi.
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