In 1917, Einstein put the concept into the more precise form which
now prevails. According to a theory previously advanced by Professor
Niels Bohr of Copenhagen, an atomic or molecular structure does not
change its configuration, or dissipate away its energy, by gradual
stages. Gradualness is driven out of physics, and discontinuity takes
its place. An atomic structure has a number of possible states or
configurations which are entirely distinct and detached one from
another, just as a weight placed on a staircase has only a possible
number of positions; it may be 3 stairs up, or 4 or 5, but cannot
be 3¼ or 3¾ stairs up. The change from one position to another is
generally effected through the medium of radiation. The system can
be pushed upstairs by absorbing energy from radiation which falls on
it, or may move downstairs to a state of lower energy and emit energy
in the form of radiation in so doing. Only radiation of a certain
definite colour, and so of a certain precise wave-length, is of any
account for effecting a particular change of state. The problem of
shifting an atomic system is like that of extracting a box of matches
from a penny-in-the-slot machine; it can only be done by a special
implement, to wit a penny, which must be of precisely the right size
and weight—a coin which is either too small _or too large_, too
light _or too heavy_, is doomed to fail. If we pour radiation of the
wrong wave-length on to an atom, we may reproduce the comedy of the
millionaire whose total wealth will not procure him a box of matches
because he has not a loose penny, or we may reproduce the tragedy of
the child who cannot obtain a slab of chocolate because its hoarded
wealth consists of farthings and half-pence, but we shall not disturb
the atom. When mixed radiation is poured on to a collection of atoms,
these absorb the radiation of just those wave-lengths which are needed
to change their internal states, and none other; radiation of all other
wave-lengths passes by unaffected.
Public-domain text, read in full here on John Shaqi.
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