These lines are very unequally distributed, some being crowded together
in masses, while others are extremely faint, and are separated by large
intervals. Their position is well marked and determined, no matter from
what source we obtain our beam of sunlight. Whether the spectrum be
produced from the sun itself, or from the reflected light proceeding
from the moon or planets, they are still found in the same place; only
that in the latter case they are not so numerous, on account of the
light being much fainter. For many years the cause of these lines
remained a complete mystery, and it was not until Bunsen and Kirchhoff
undertook their investigation that a satisfactory explanation of their
origin was arrived at. In order to explain this, we must consider
briefly the properties of the spectra of flames, and other luminous
bodies.
If, instead of the light of the sun, we examine prismatically the light
given off by an incandescent body, such as a white-hot piece of
platinum, we shall find that the lines seen in the solar spectrum are
absent, and that we have a continuous band of coloured light quite
uninterrupted by dark spaces or bands. The same absence of lines is seen
in the spectra of the electric light and the flame of an ordinary
candle, the light in each of these cases being produced by particles of
carbon in a state of vivid incandescence. But if we examine the flame of
incandescent gases, we shall find a spectrum of an entirely new kind.
Thus if we examine an ordinary gaslight through a slit with a prism, we
shall obtain a continuous spectrum, in consequence of the luminous
portion of the flame consisting of solid carbon in a state of
incandescence; but if we turn down the flame, so as to lessen the amount
of carbon to be burned, we shall find the whole of that body is
converted into feebly luminous gas, giving off a faint reddish blue
light. If we now again examine it in the same manner, we shall find that
the spectrum produced consists of black spaces, here and there crossed
by a few faint coloured lines or bands. The reason of this is obvious:
in the faint flame caused by the carbon and hydrogen in a state of
luminous vapour, which only have a few of the colours of the spectrum,
which, when passed through the prism, fall into their proper places. All
substances with which we are acquainted are capable of being converted
into luminous vapour by means of heat, and when thus burnt produce
flames of more or less faint luminosity, generally characteristically
coloured. A piece of soda inserted in the wick of a spirit-lamp gives a
yellow tinge to the flame; a morsel of saltpetre (nitrate of potash) or
nitrate of strontia will give a purple and crimson tint respectively.
These hues are caused by the metals sodium, potassium, and strontium
contained in these salts being converted into luminous vapour. On
analyzing these coloured flames with a prism, as before, we should find
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