in the case of the soda a single broad yellow line, situated just in the
middle of the yellow portion of the spectrum, the rest of the space
where the spectrum should be being perfectly dark. The reason of this is
pretty simple. Sodium burns with a pure yellow flame, consequently when
passed through a prism it cannot split into any other colours, but takes
its place in the position belonging to yellow of that particular hue.
Were it a little more orange or green in tint, it would take its place
nearer to the red or violet end of the spectrum. The light from
saltpetre, which contains potassium may next be examined. It will be
found to tinge the flame with the spirit-lamp of a beautiful purple. We
can almost guess what will happen when this flame is submitted to the
action of the prism. We shall find that the purple light emitted will
split into red and violet, which will immediately arrange themselves in
their proper positions according to their hues. If in like manner we
substitute nitrate of strontia for saltpetre, we shall get a splendid
crimson flame which is decomposed by the prism into red, orange, or
blue.
On submitting the compounds of the other elements to the same tests, we
shall find that each of them, when converted into luminous gas, is
capable of producing coloured lines of various kinds when the light of
their flames is passed through a prism. If, therefore, we had a number
of salts of whose composition we were ignorant, all we need do is to
burn them in a spirit-lamp, and by the number and position in the lines
of their spectra we should be able to tell immediately of what they were
composed.
The spectra of nearly all the elements capable of being connected with
luminous gas have been determined with great accuracy. Perhaps the
number and position of the lines of a few spectra will be interesting to
the student.
_Sodium._—This is the metallic base of soda salts, and gives a double
bright yellow line in the middle of the yellow.
_Potassium._—The base of the various salts of potash. It gives one line
in the extreme red, one in the middle of the red, one in the violet, and
a peculiar glow in the centre of the spectrum.
_Strontium._—The base of the strontia salts, of which the nitrate is
used as the principal ingredient in the red fire of the theatres. It
gives a group of lines in the red and orange, and a beautiful blue one
in the middle of the blue.
_Barium._—The base of the baryta salts, one of which is used in making
green fire. It gives several strong lines in the green, and a few in the
red, orange, and yellow.
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