In ordinary chemical changes it is the _molecules_ (groups of
atoms) which are altered or rearranged; in radioactive change
the atoms themselves suffer disintegration and rearrangements.
The energy of radioactivity, then, is--according to the accepted
view--intra-atomic--stored-up energy within the atom itself. It was
calculated by Prof. Curie that the energy of one gram of radium would
suffice to lift a weight of 500 tons to a height of one mile. If it
were possible to obtain one cubic centimeter (a thimbleful) of the
“emanation” from radium in the form of a gas, we should find that it
possessed the power, altogether, of emitting more than seven million
calories of heat! A thimbleful of this invisible gas would be more
than sufficient to raise 15,000 pounds of water 1°. But in every mass
of radium, small or large, not more than 13 trillionths of it is
undergoing change per second.
“The processes occurring in the radio-elements,” says Rutherford again,
“are of a character quite distinct from any previously observed in
chemistry. Although it has been shown that the radioactivity is due
to the spontaneous and continuous production of new types of active
matter, the laws which control this production are different from the
laws of ordinary chemical reactions. It has not been found possible in
any way to alter either the rate at which the matter is produced or its
rate of change when produced. Temperature, which is such an important
factor in altering the rate of chemical reactions, is, in these cases,
entirely without influence. In addition, no ordinary chemical change is
known which is accompanied by the expulsion of charged atoms with great
velocity.... Besides their high atomic weights, [they] do not possess
in common any special chemical characteristics which differentiate them
from the other elements.”
It was early observed by Curie and Laborde that the temperature of a
radium salt is always a degree or two above that of the atmosphere,
and they estimated that a gram of pure radium would emit about 100
gram-calories per hour. Giesel later showed that radium was always at a
temperature 5° higher than the surrounding air, regardless of what the
temperature of the air might be. This continues unchanged whether the
temperature of the surroundings be 250° below zero Centigrade, or in
the intense heat of an electric furnace.
Public-domain text, read in full here on John Shaqi.
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