Radium is not only continually losing matter and energy as electricity,
but it is also losing energy as heat. Professor and Mme. Curie
discovered that any substance placed near radium becomes itself
a _false_ radium. This applies to all substances. The acquired
radioactivity persists for many hours, or even days, after the removal
of the radium. In the case of zinc, these secondary radiations were
found to be four times as intense as ordinary uranium. It vanishes
sooner or later upon the removal from the neighborhood of the potent
radium.
The radioactive something which passes out of radium was not the
already known group of Alpha, Beta and Gamma rays, but an _emanation_
akin to gas. Rutherford, its original discoverer, was not sure that
it was a gas, so he cautiously gave it the name _emanation_. When the
radium was heated, or dissolved in water, the quantity of emanation
was greatly increased, which seemed to show that it was a gas of
some kind occluded (bound up) in the radium. The quantity obtained
was insufficient to bring the emanation within the testing power of
spectroscope or balance.
Nevertheless, the emanation has been detected, and investigated by the
electroscope, which measures the radium rays by the power to discharge
its electrified gold leaves. “The electroscope is about a million
times more sensitive than the most sensitive spectroscope and yet the
spectroscope is capable of detecting easily the millionth part of a
milligram of matter” (Duncan).
Calculations made by Rutherford show that if a thimbleful of this
active gas could be collected, the bombardment of its powerful rays
would heat to a red heat, or even might melt down, the walls of the
glass containing it. The emanation emits only Alpha rays (or particles)
forming helium.
The radium from which the emanation has been abstracted, after the
lapse of an hour or so, loses 75% of its activity. During the course
of a single month, radium will be found to have restored all its lost
emanation. In thirty days it will have regained all its original
activity. It was soon discovered that the emanation abstracted from the
radium loses its radioactivity at the same rate and according to the
same laws as the de-emanated radium regains it. The radium is therefore
said to be “in equilibrium with its products.”
Since these processes are wholly outside the sphere of known
controllable forces, and cannot be created, altered or destroyed--“since
the process is independent of the chemical form of the radium, whether
bromide, chloride, sulphate, etc., we are absolutely shut up to the
conviction that it is a function of the atom. We are in the presence of
an actual decay of the atom. The atom of radium breaks down into atoms
of emanation and the atoms of emanation in their turn break down into
something else. The activity of emanation decays and falls to half value
in about 3.7 days.”
Public-domain text, read in full here on John Shaqi.
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