The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy SteelColvin, Fred H. (Fred Herbert)
Science
The Working of Steel: Annealing, Heat Treating and Hardening of Carbon and Alloy Steel
Colvin, Fred H. (Fred Herbert)
Steel
It may readily be understood that an alloy containing four essential
elements, namely: iron, carbon, tungsten and chromium, is one whose
study presents problems of extreme complexity. It is possible that
complex carbides may be formed, as in chromium steels, and that
compounds between iron and tungsten exist. Behavior of these
combinations on heating and cooling must be better known before
we are able to explain many peculiarities of tungsten steels.
MOLYBDENUM
Molybdenum steels have been made commercially for twenty-five years,
but they have not been widely exploited until since the war. Very
large resources of molybdenum have been developed in America, and
the mining companies who are equipped to produce the metal are
very active in advertising the advantages of molybdenum steels.
It was early found that 1 part molybdenum was the equivalent of from
2 to 2-1/2 parts of tungsten in tool steels, and magnet steels. It
fell into disrepute as an alloy for high-speed tool steel, however,
because it was found that the molybdenum was driven out of the
surface of the tool during forging and heat treating.
Within the last few years it has been found that the presence of
less than 1 per cent of molybdenum greatly enhances certain properties
of heat-treated carbon and alloy steels used for automobiles and
high-grade machinery.
In general, molybdenum when added to an alloy steel, increases the
figure for reduction of area, which is considered a good measure
of "toughness." Molybdenum steels are also relatively insensible
to variations in heat treatment; that is to say, a
chromium-nickel-molybdenum steel after quenching in oil from 1,450 deg.F.
may be drawn at any temperature between 900 and 1,100 deg.F. with
substantially the same result (static tensile properties and hardness).
SILICON
Silicon prevents, to a large extent, defects such as gas bubbles
or blow holes forming while steel is solidifying. In fact, steel
after it has been melted and before it has been refined, is "wild"
and "gassy." That is to say, if it would be cast into molds it
would froth up, and boil all over the floor. A judicious amount
of silicon added to the metal just before pouring, prevents this
action--in the words of the steel maker, silicon "kills" the steel.
If about 1.75 per cent metallic silicon remains in a 0.65 carbon
steel, it makes excellent springs.
PHOSPHORUS
Phosphorus is one of the impurities in steel, and it has been the
object of steel makers for years to eliminate it. On cheap grades
of steel, not subject to any abnormal strain or stress, 0.1 per
cent phosphorus is not objectionable. High phosphorus makes steel
"cold short," i.e., brittle when cold or moderately warm.
SULPHUR
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