Things a Boy Should Know About Electricity: Second EditionSt. John, Thomas M. (Thomas Matthew)
Science
Things a Boy Should Know About Electricity: Second Edition
St. John, Thomas M. (Thomas Matthew)
Electricity
=45. The Simple Cell.= It has been stated that two different kinds of
electrifications may be produced by friction; one positive, the other
negative. Either can be produced, at will, by using proper materials.
Fig. 37 shows a section of a _simple cell_; Fig. 38 shows another view.
Cu is a piece of copper, and Zn a piece of zinc. When they are placed
in dilute sulphuric acid, it can be shown by delicate apparatus that
they become charged differently, because the acid acts differently
upon the plates. They become charged by chemical action, and not by
friction. The zinc is gradually dissolved, and it is this chemical
burning of the zinc that furnishes energy for the electric current in
the simple cell. The electrification, or charge, on the plates tends to
flow from the place of higher to the place of lower potential, just as
water tends to flow down hill. If a wire be joined to the two metals, a
constant current of electricity will flow through it, because the acid
continues to act upon the plates. The simple cell is a _single-fluid_
cell, as but one liquid is used in its construction.
=45a. Plates and Poles.= The metal strips used in voltaic cells are
called _plates_ or _elements_. The one most acted upon by the acid
is called the positive (+) plate. In the simple cell the zinc is the
+ plate, and the copper the negative (-) plate. The end of a wire
attached to the - plate is called the + pole, or electrode. Fig. 37
shows the negative (-) electrode as the end of the wire attached to the
+ plate.
=46. Direction of Current.= In the cell the current passes from the
zinc to the copper; that is, from the positive to the negative plate,
where bubbles of hydrogen gas are deposited. In the wire connecting the
plates, the current passes from the copper to the zinc plate. In most
cells, carbon takes the place of copper. (See "Study," § 268.)
=47. Local Currents; Amalgamation.= Ordinary zinc contains impurities
such as carbon, iron, etc., and when the acid comes in contact with
these, they form with the zinc a small cell. This tends to eat away the
zinc without producing useful currents. The little currents in the cell
from this cause are called _local currents_. (See "Study," Exp. 111, §
273.) This is largely overcome by coating the zinc with mercury. This
process is called _amalgamation_. It makes the zinc act like pure zinc,
which is not acted upon by dilute sulphuric acid when the current does
not pass. (See "Study," § 257, 274.)
=48. Polarization of Cells.= Bubbles of hydrogen gas are formed when
zinc is dissolved by an acid. In the ordinary simple cell these bubbles
collect on the copper plate, and not on the zinc plate, as might be
expected. The hydrogen is not a conductor of electricity, so this film
of gas holds the current back. The hydrogen acts like a metal and sets
up a current that opposes the zinc to the copper current. Several
methods are employed to get rid of the hydrogen. (See "Study," § 278,
279, 280.)
CHAPTER IV.
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