Tomato products: pulp, ketchup, and chili sauce.Bigelow, W. D. (Willard Dell)
Science
Tomato products: pulp, ketchup, and chili sauce.
Bigelow, W. D. (Willard Dell)
Tomato products
[14] Methods of Analysis of the Association of Official Agricultural
Chemists (1919).
Determination of Acidity
Accurate results cannot be obtained by the titration of tomato products
in the presence of the insoluble solids. If it be desired to determine
the acidity in the entire sample of tomatoes or tomato pulp rather than
in the expressed juice, the insoluble solids should first be removed
by the method given in the determination of insoluble solids or by
filtration through filter paper. The per cent of acid given in Tables
2 and 3 was obtained by titrating the liquor obtained by filtering the
pulp. In products of this nature, the addition of an alkali causes a
brownish color which has a tendency to obscure the end point shown
by the indicator. To obviate this, the sample should be diluted to
at least 200 cc. and a larger amount of indicator employed than is
necessary with a clear solution. The following details are suggested.
Dilute 20 grams of the filtrate under examination with over 200
cc. of water. Add at ½ cc. of phenolphthalein solution (prepared
by dissolving 1 gram of phenolphthalein in 100 cc. of 95 per cent
alcohol) and titrate with sodium hydroxide until the end point is
obtained. Add 1 cc. of tenth-normal hydrochloric acid, heat the
solution quickly to boiling and boil one minute to expel carbon
dioxide. Cool the solution quickly to about room temperature, and then
add tenth-normal sodium hydroxide until the end point is obtained.
The volume of hydrochloric acid added must, of course, be taken into
consideration in the final result. The filtrate may also be titrated
direct with tenth-normal sodium hydroxide solution with satisfactory
results.
Determination of Salt
This laboratory has been using the following rapid method which gives
results agreeing closely with results obtained by the analysis of the
ash:
Weigh out 20 grams of pulp, dilute in a volumetric flask to 200 cc.,
filter and titrate an aliquot portion with standard silver nitrate
solution, using potassium chromate as indicator. The acidity of tomato
pulp is not sufficient to interfere with this determination.
DETERMINATION OF SPECIFIC GRAVITY[15]
[15] All specific gravities given in this bulletin are on a 20°C/20°C
basis.
The specific gravity of tomato pulp is used as one criterion for
establishing the value of pulp that is offered for sale and is also
used in connection with the manufacture of pulp to determine the point
at which evaporation should be stopped.
In the former case there is ample time for making the examination,
and conditions may be established which permit a reasonable degree of
accuracy in the work.
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