Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
clothes, and no attempt has been made to remove the remaining acid by
washing or neutralization, a sufficient quantity will be present even
after several weeks to admit of being satisfactorily detected by
chemical analysis.
The following are the steps of the process which appear to me the most
delicate and equivocal. Cut away the stained spots; boil them for a
minute or two in several successive small portions of distilled water;
and filter if necessary. Next prove the acidity of the fluid by litmus,
and likewise by the taste if the quantity of solution is large enough to
allow of so coarse a test being used; and with a few drops ascertain the
existence of sulphuric acid in one form or another by nitrate of baryta
and nitric acid, as mentioned in the process for the pure diluted acid.
If no precipitate appears, the search for sulphuric acid is at an end.
But if a precipitate is produced, ascertain the absence of bisulphates
and sulphates by proving the absence of bases, according to the method
described in the process for the simple diluted acid. If, however, bases
be found in material proportion to the acid, the analysis is subject to
all the difficulties mentioned above in speaking of the detection of the
diluted acid in similar circumstances.
_Process for the contents of the stomach and other complex
mixtures._—When sulphuric acid has been mixed with various mineral and
organic substances, it may in no long time cease to exist in the free
state. Part may be decomposed by organic matter in the way formerly
mentioned. Or the whole may be neutralized at once by earthy or alkaline
carbonates, administered purposely as antidotes. Or it may also be
neutralized more slowly by the gradual development of ammonia in
consequence of the decay of the animal matter co-existing in the
mixture. Thus in a case mentioned by Mertzdorff of a child killed in
twelve hours with sulphuric acid, the contents of the stomach did not
redden litmus, but on the contrary had an ammoniacal odour; and they
contained a considerable quantity of a soluble sulphate, probably the
sulphate of ammonia.[236] In like manner MM. Orfila and Lesueur found
that when this acid was left some months in a mixture which contained
putrefying azotized matter, it was gradually neutralized by
ammonia.[237] It appears from Orfila’s latest researches,[238] that in
most cases of acute poisoning with this substance some free acid will be
found in the contents or tissues of the stomach, provided alkalis or
earths were not given as antidotes, and the examination of the body be
made before decay sets in.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account