Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
In solution many tests will detect it, such as chlorine, nitric acid,
corrosive sublimate, acetate of lead, protonitrate of mercury, muriate
of platinum, and starch with chlorine or nitric acid. Chlorine or nitric
acid forms a brown or orange-coloured solution by disengaging iodine.
Corrosive sublimate forms a fine carmine-red precipitate, the biniodide
of mercury; acetate of lead a fine yellow precipitate, the iodide of
lead; protonitrate of mercury a yellow protiodide of mercury, which
gradually fades into a dirty brown. Solution of starch, followed by
chlorine in solution or in vapour, strikes a deep blue colour, which, if
the fluid is sufficiently diluted, disappears on boiling, reappears on
sudden cooling, and is permanently removed by a stream of sulphuretted
hydrogen gases. Of these tests the most characteristic is starch with
chlorine; and it is also extremely delicate. Too much chlorine however
bleaches the blue colour away.
In compound mixtures most and sometimes all of these tests are useless.
If the mixture is deeply coloured, none will act characteristically. If
carbonate of potass be present in such proportion as is often met with
in the shops, the tests cannot be trusted to.
_Process for Compound Mixtures._—The following method of analysis is
applicable to all mixtures, organic and inorganic. Add water, if
necessary, and filter; and if the fluid which passes through is
tolerably free from colour, test a little of it with solution of starch
and chlorine. If the colour is too deep to admit of this trial, or the
test on trial does not act, unite the fluid and solid parts and transmit
sulphuretted hydrogen to convert any free iodine into hydriodic acid.
Drive off the excess of gas, supersaturate with a considerable excess of
potass, filter, and evaporate to dryness. Char the residue at a low red
heat in a covered crucible; pulverize the charcoaly mass, and exhaust
with water. This solution will probably act characteristically with
starch and chlorine; but on the whole it is better in the first instance
to remove some of the salts by evaporating to dryness, and exhausting
the residuum with alcohol. The alcoholic solution contains the
hydriodate of potass, with some other salts; and on being evaporated to
dryness, a residuum is left, on which, when dissolved in water, the
starch and chlorine will act characteristically. No other test is
necessary; and frequently no other test will act, on account of
co-existing salts.
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