Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
distinctive, it may be right to subject it to a farther test when the
metal is not previously exhibited with its characteristic properties.
For this purpose it is sufficient to cut away with a file the portion of
the tube which contains the sublimate, to boil it in another tube with a
few drops of distilled water till the sublimate disappear, and then to
test the solution with one of the fluid tests to be presently described,
the ammoniacal nitrate of silver.
After all that has been recently written as to the old and newer
processes for detecting arsenic, I must nevertheless avow my conviction,
that for solid arsenic no test is, for medico-legal purposes, at once so
satisfactory, convenient, and delicate as the test of reduction,
especially with the addition of the supplementary test of oxidation.
That other methods are still more delicate may be readily granted. But
where the suspected substance is in the solid form, what possible
occasion can there be for a method more delicate than one which will
detect a 300th part of a grain? A method ten times less so would meet
every case in actual practice.—A variety of supplementary tests have
been proposed. But they are all greatly inferior in facility, or
conclusiveness, or both, to the process of oxidation, and ought
therefore to be expelled from medico-legal practice,—not even excepting
the alliaceous odour of metallic arsenic in the act of subliming, a
character, the fallaciousness of which was long ago pointed out by
myself as well as others, and to which a preposterous importance has
been attached in some late inquiries. The reader will find in the last
edition of this work an attempt to estimate the value of various tests
supplementary to that of reduction. This disquisition is now omitted, as
it seems no longer necessary.
_Of the Tests for Oxide of Arsenic in Solution._
Oxide of arsenic in a state of solution may be detected in one of four
ways; by what are called the liquid tests; by precipitating it with one
of these, and subliming metallic arsenic from the precipitate, which
method is usually termed the reduction process; by Marsh’s method, which
consists in disengaging it in the form of arseniuretted-hydrogen gas,
and decomposing the gas by combustion; or by the method of Reinsch, in
which metallic arsenic is deposited on the surface of copper, and then
separated by heat for farther examination.
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