Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
accused of administering the poison was acquitted. An extended inquiry,
however, was in consequence undertaken by the Parisian Academy of
Medicine at the request of the French government. And the result was
that no arsenic could be detected in the glass tubes used by MM. Ozanam
and Idt; and that although arsenic is sometimes used in glass-making,
and a trace of it may be retained in some opaque glasses or enamels, it
cannot be detected by any process of analysis in any of the clear glass
met with in commerce,[514] the whole arsenic being volatilized during
the manufacture of the glass.
It may therefore be safely laid down that the appearances exhibited by a
well-formed arsenical crust, even in the minute quantity of a 300th part
of a grain, are imitated by no substance in nature which can be sublimed
by the process for the reduction of arsenic.
But should farther evidence be required as to the nature of the crust,
this may be obtained by subjecting it to oxidation by heat.
The best method of doing so is to heat the ball containing the flux
deprived of arsenic, to attach a bit of glass tube to its end, and to
draw this gently off in the spirit-flame, taking care to prevent the
flux being driven forward on the crust. This being done, the whole
crust, or, if it is large, a portion of it, is to be chased up and down
the tube with a small spirit-lamp flame till it is all converted into a
white powder. In order to show the crystalline form of the powder
distinctly, let the flame be reduced to the volume of a pea by drawing
in the wick, and let the part of the tube containing the oxide be held
half an inch or an inch above it. By repeated trials sparkling crystals
will at length be formed, which are octaedres,—the crystalline form of
arsenious acid. The triangular facettes of the octaedres may be
sometimes seen with the naked eye, though the original crust was only a
fiftieth of a grain or even less; and they may be always seen with a
lens of four powers, the tube being held between the eye and a lighted
candle or a ray of sunshine, either of which is preferable to diffuse
daylight for making this observation.—For the success of the oxidation
test it is indispensable that the inside of the tube be not soiled with
an alkaline flux: because the alkali would unite with the oxide. It is
also requisite not to heat the tube suddenly to redness before the oxide
is sublimed; because then the oxide is apt to unite with the glass,
forming a white, opaque enamel. The physical characters of the sublimed
oxide are so delicate and precise, that they may be accurately
distinguished, even when those of the metallic crust are obscure, owing
to its minuteness. Sometimes too, the metal may be so scanty that it is
oxidated at once in the act of subliming, and never presents the
appearance of a metallic crust. Although the characters of the
crystalline oxide in either of these cases are very precise and
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account