Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
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Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
Some experience is required to apply this process successfully. But with
due attention it furnishes conclusive evidence with great delicacy and
precision. A solution containing only a millionth part of oxide of
arsenic will part with it readily in the form of arseniuretted-hydrogen;
and the slightest trace of that gas in the hydrogen is indicated by the
method recommended above.—The process is compounded of Mr. Marsh’s
original discovery, the supplementary test of reduction in the exit-tube
recommended by Berzelius,[526] and the formation and examination of the
oxide proposed by myself.[527]—With certain precautions and modes of
manipulating, it is applicable to the most complex organic fluids, as
well as to simple solutions.
The discovery of Mr. Marsh had not been long made before the test in its
original simple form was found liable to divers important fallacies. It
appeared, for example, that antimony yields very nearly the same
appearance of metallic crust and of white powder, according to the
position of the porcelain in the flame; that some porcelains glazed with
oxide of zinc are similarly stained by a flame of simple hydrogen gas;
that a great variety of metallic salts, if spirted up into the
exit-tube, undergo reduction in the flame, and cause imitative stains on
the porcelain; that iron-salts seems to form stains from the same
chemical action as what occurs in the case of arsenic; and that certain
compounds of phosphorous acid with ammonia and animal matter, or even
mere animal matters themselves, will in some circumstances produce a
stain more or less similar to that which is occasioned by arsenic.
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