Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
There is no doubt, that the resemblance of most of these spurious stains
to an arsenical crust has been much exaggerated. But still the
similarity is sufficient to satisfy every impartial judge, that the mere
production of a brilliant metallic, or white powdery stain, or both,
upon porcelain, is not conclusive evidence of the detection of arsenic
in medico-legal inquiries. It is strong presumptive evidence; and the
non-production of such stains is absolute proof that arsenic is not
present. But in order to obtain irrefragable proof of its presence, the
substance which forms the crusts and stains must be subjected to farther
examination. And such is the object of the supplementary methods in the
process detailed above. That process is perfectly free of fallacy. No
substance yet known but arsenic can yield the succession of phenomena
which have been detailed. My opinion farther is, that the process may be
safely simplified by withdrawing Berzelius’s supplementary test of
reduction in the exit-tube, and retaining the test of oxidation only,
with the examination of the oxide by liquid reagents. I have retained
the former in deference to the opinion expressed by a committee
appointed by the French Institute, who examined the whole subject with
unwearied zeal, but who, it may be observed, seem never to have had in
their view the check-test of oxidation; which, with the consecutive
tests, is superior in conclusiveness to the check of reduction only.
_Reinsch’s process_, like the former, has been inconveniently called a
new test for arsenic. The fact discovered by Dr. Reinsch is valueless as
supplying a mere test; but it forms the ground-work of the best process
of all yet proposed for the detection of arsenic in solution. The
discovery is, that arsenic in solution is deposited in the metallic
state upon copper-leaf, when the fluid is acidulated with hydrochloric
acid, and heated till it boils gently or is about to do so; and that by
heating the copper gently in a glass tube the arsenic is sublimed from
it in the form of oxide or metal according to the quantity present.[528]
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