Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
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Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
_Process of Reinsch._—This is the simplest and easiest of all. Remove in
the first place any white or gray powder which can be detached from the
mixture; and either subject it to the process of reduction by charcoal
or soda-flux, as described at p. 203, or dissolve it in boiling
distilled water and subject the solution to the three liquid reagents,
p. 207, or if there be enough, examine it in both ways. If arsenic be
thus obtained, it is seldom necessary to proceed any farther. But if
not, cut all soft solids into small fragments, add distilled water if
necessary, then add hydrochloric acid to the amount of a tenth of the
whole mixture, and more if the subject of analysis be decayed and
ammoniacal, so that there may be a decided excess of acid. Boil gently
for an hour, or until all soft solids be either dissolved or broken down
into fine flakes and grains. Filter through calico; bring the filtered
fluid again to the boiling point; and then proceed as described for
Reinsch’s method in simple arsenical solutions [p. 214].
The only important precaution to be attended to in employing this
process is to take care that the water, hydrochloric acid, and calico
are free of accidental impregnation with arsenic. This is guarded
against by applying the process to them in the first instance. I have
lately employed this method of analysis with success in two medico-legal
cases where the bodies had been buried for several months, and where the
quantity of arsenic must have been very minute. Satisfactory evidence
was obtained from a sixth part of the stomach, and also from the same
proportion of the liver.
_Process of Marsh._—The chief difficulties in applying the process of
Marsh to complex organic mixtures arise from the tendency of oxide of
arsenic to adhere with obstinacy to some organic principles in the solid
state, and from the liability of the gas disengaged in the apparatus to
raise organic fluids in a fine froth, which breaks up slowly, and is
therefore apt to pass over into the exit-tube. Many contrivances have
been devised, to meet these difficulties, especially by the French
chemists and toxicologists, whose attention was turned earnestly to the
subject by the investigations carried on in certain late criminal trials
of great interest and importance. The various devices now alluded to
were subjected to trial in 1841 by a Committee of the French Institute;
who came to the opinion that the following method suggested by MM.
Flandin and Danger is the most convenient and comprehensive.[533]
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