Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physicChristison, Robert, Sir
Science
Treatise on Poisons: In relation to medical jurisprudence, physiology, and the practice of physic
Christison, Robert, Sir
Medical jurisprudence; Toxicology
_Process for Organic Mixtures._—If sulphuret of arsenic be present in
such mixtures in appreciable quantity, the particles, owing to their
intense yellow colour, will be visible in any mass which has not the
same tint. From this state of admixture they may be removed by adding
caustic ammonia which dissolves sulphuret of arsenic; and the solution,
on being acidulated with muriatic acid, will deposit the sulphuret
sufficiently pure for undergoing the process of reduction.
Sulphuret of arsenic sometimes exists in small quantity in the stomach,
although the poison was given in the form of oxide; for a portion of the
oxide is subject to be converted into the sulphuret by hydrosulphuric
acid gas evolved in the stomach after death.[564] In every instance of
the kind yet carefully examined a large proportion of the oxide has
remained unacted on, although the intense colour of the mixed sulphuret
makes it appear as if that were the only compound present.
7. _Arseniuretted-Hydrogen._
This compound presents the form of a colourless gas, possessing a fetid
garlicky odour, a density of nearly 2·7, and great virulence as a
poison. It is mentioned here, because accidental poisoning with it has
happened occasionally within a few years, chiefly owing to the
occasional adulteration of sulphuric acid with arsenic, and the
liability of the arsenic to form arseniuretted-hydrogen when such
sulphuric acid is used to prepare hydrogen gas. Dr. O’Reilly has
mentioned a melancholy instance of a young chemist losing his life in
this way.[565] Dr. Schlinder of Greifenberg has related another, which
did not prove fatal.[566] And it is well known that the German chemist
Gehlen lost his life by accidentally breathing arseniuretted-hydrogen
while engaged in examining its chemical properties.[567] It is an
inflammable body; and its presence in any other gas is easily detected
by burning it according to the method of Marsh.
SECTION II.—_Of the Action of Arsenic and the Symptoms it excites in
Man._
It is now generally admitted that arsenic produces in the living body
two classes of phenomena,—or that, like the narcotico-acrids, it has a
twofold action. One action is purely irritant, by virtue of which it
induces inflammation in the alimentary canal and elsewhere. The other,
although it seldom occasions symptoms of narcotism properly so called,
yet obviously consists in a disorder of parts or organs remote from the
seat of its application.
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