Beagle Expedition (1831-1836); Geology -- South America; Volcanoes
One side of Fresh-water Bay, in James Island, is formed by the wreck of
a large crater, mentioned in the last chapter, of which the interior
has been filled up by a pool of basalt, about two hundred feet in
thickness. This basalt is of a grey colour, and contains many crystals
of glassy albite, which become much more numerous in the lower,
scoriaceous part. This is contrary to what might have been expected,
for if the crystals had been originally disseminated in equal numbers,
the greater intumescence of this lower scoriaceous part would have made
them appear fewer in number. Von Buch has described a stream of
obsidian on the Peak of Teneriffe, in which the crystals of feldspar
become more and more numerous, as the depth or thickness increases, so
that near the lower surface of the stream the lava even resembles a
primary rock. (“Description des Isles Canaries” pages 190 and 191.) Von
Buch further states, that M. Dree, in his experiments in melting lava,
found that the crystals of feldspar always tended to precipitate
themselves to the bottom of the crucible. In these cases, I presume
there can be no doubt that the crystals sink from their weight. (In a
mass of molten iron, it is found (“Edinburgh New Philosophical Journal”
volume 24 page 66) that the substances, which have a closer affinity
for oxygen than iron has, rise from the interior of the mass to the
surface. But a similar cause can hardly apply to the separation of the
crystals of these lava-streams. The cooling of the surface of lava
seems, in some cases, to have affected its composition; for Dufrenoy
(“Mem. pour servir” tome 4 page 271) found that the interior parts of a
stream near Naples contained two-thirds of a mineral which was acted on
by acids, whilst the surface consisted chiefly of a mineral
unattackable by acids.) The specific gravity of feldspar varies from
2.4 to 2.58, whilst obsidian seems commonly to be from 2.3 to 2.4; and
in a fluidified state its specific gravity would probably be less,
which would facilitate the sinking of the crystals of feldspar. (I have
taken the specific gravities of the simple minerals from Von Kobell,
one of the latest and best authorities, and of the rocks from various
authorities. Obsidian, according to Phillips, is 2.35; and Jameson says
it never exceeds 2.4; but a specimen from Ascension, weighed by myself,
was 2.42.) At James Island, the crystals of albite, though no doubt of
less weight than the grey basalt, in the parts where compact, might
easily be of greater specific gravity than the scoriaceous mass, formed
of melted lava and bubbles of heated gas.
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