Beagle Expedition (1831-1836); Geology -- South America; Volcanoes
The sinking of crystals through a viscid substance like molten rock, as
is unequivocally shown to have been the case in the experiments of M.
Dree, is worthy of further consideration, as throwing light on the
separation of the trachytic and basaltic series of lavas. Mr. P. Scrope
has speculated on this subject; but he does not seem to have been aware
of any positive facts, such as those above given; and he has overlooked
one very necessary element, as it appears to me, in the
phenomenon—namely, the existence of either the lighter or heavier
mineral in globules or in crystals. In a substance of imperfect
fluidity, like molten rock, it is hardly credible, that the separate,
infinitely small atoms, whether of feldspar, augite, or of any other
mineral, would have power from their slightly different gravities to
overcome the friction caused by their movement; but if the atoms of any
one of these minerals became, whilst the others remained fluid, united
into crystals or granules, it is easy to perceive that from the
lessened friction, their sinking or floating power would be greatly
increased. On the other hand, if all the minerals became granulated at
the same time, it is scarcely possible, from their mutual resistance,
that any separation could take place. A valuable, practical discovery,
illustrating the effect of the granulation of one element in a fluid
mass, in aiding its separation, has lately been made: when lead
containing a small proportion of silver, is constantly stirred whilst
cooling, it becomes granulated, and the grains of imperfect crystals of
nearly pure lead sink to the bottom, leaving a residue of melted metal
much richer in silver; whereas if the mixture be left undisturbed,
although kept fluid for a length of time, the two metals show no signs
of separating. (A full and interesting account of this discovery, by
Mr. Pattinson, was read before the British Association in September
1838. In some alloys, according to Turner “Chemistry” page 210, the
heaviest metal sinks, and it appears that this takes place whilst both
metals are fluid. Where there is a considerable difference in gravity,
as between iron and the slag formed during the fusion of the ore, we
need not be surprised at the atoms separating, without either substance
being granulated.) The sole use of the stirring seems to be, the
formation of detached granules. The specific gravity of silver is 10.4,
and of lead 11.35: the granulated lead, which sinks, is never
absolutely pure, and the residual fluid metal contains, when richest,
only 1/119 part of silver. As the difference in specific gravity,
caused by the different proportions of the two metals, is so
exceedingly small, the separation is probably aided in a great degree
by the difference in gravity between the lead, when granular though
still hot, and when fluid.
Public-domain text, read in full here on John Shaqi.
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