Some considerable masses of wacke, which are associated with these basaltic strata, and which likewise occur in the basal series on the coast, especially at Quail Island, are curious. They consist of a pale yellowish- green argillaceous substance, of a crumbling texture when dry, but unctuous when moist: in its purest form, it is of a beautiful green tint, with translucent edges, and occasionally with obscure traces of an original cleavage. Under the blowpipe it fuses very readily into a dark grey, and sometimes even black bead, which is slightly magnetic. From these characters, I naturally thought that it was one of the pale species, decomposed, of the genus augite;—a conclusion supported by the unaltered rock being full of large separate crystals of black augite, and of balls and irregular streaks of dark grey augitic rock. As the basalt ordinarily consists of augite, and of olivine often tarnished and of a dull red colour, I was led to examine the stages of decomposition of this latter mineral, and I found, to my surprise, that I could trace a nearly perfect gradation from unaltered olivine to the green wacke. Part of the same grain under the blowpipe would in some instances behave like olivine, its colour being only slightly changed, and part would give a black magnetic bead. Hence I can have no doubt that the greenish wacke originally existed as olivine; but great chemical changes must have been effected during the act of decomposition thus to have altered a very hard, transparent, infusible mineral, into a soft, unctuous, easily melted, argillaceous substance. (D’Aubuisson “Traite de Geognosie” tome 2 page 569 mentions, on the authority of M. Marcel de Serres, masses of green earth near Montpellier, which are supposed to be due to the decomposition of olivine. I do not, however, find, that the action of this mineral under the blowpipe being entirely altered, as it becomes decomposed, has been noticed; and the knowledge of this fact is important, as at first it appears highly improbable that a hard, transparent, refractory mineral should be changed into a soft, easily fused clay, like this of St. Jago. I shall hereafter describe a green substance, forming threads within the cells of some vesicular basaltic rocks in Van Diemen’s Land, which behave under the blowpipe like the green wacke of St. Jago; but its occurrence in cylindrical threads, shows it cannot have resulted from the decomposition of olivine, a mineral always existing in the form of grains or crystals.)