Worlds in the making: The evolution of the universeArrhenius, Svante
Science
Worlds in the making: The evolution of the universe
Arrhenius, Svante
Cosmogony
By entropy we understand the quantity of heat of a body divided by its
absolute temperature. If a quantity of heat, of Q calories, of a body
at a temperature of 100° (absolute temperature, 373°) passes over to
another body of 0° (absolute temperature, 273°), the total entropy of
the two will have been decreased by Q/373, and increased by Q/273. As
the latter quantity is the greater, the entropy of the whole will have
increased. By itself, we know, heat always passes, either by radiation
or by conduction, from bodies of higher temperature to bodies of lower
temperature. That evidently implies an increase in entropy, and it is
in agreement with the law of Clausius that entropy tends to increase.
The most simple case of heat equilibrium is that in which we place a
number of bodies of unequal temperatures in an enclosure which neither
receives heat from outside nor communicates heat to the outside. In
some way or other, usually by conduction or radiation, the heat will
pass from the warmer to the colder bodies, until at last equilibrium
ensues and all the bodies have the same temperature. According to
Clausius, the universe tends to that thermal equilibrium. If it be
ever attained, all sources of motion, and hence of light, will have
been exhausted. The so-called “heat-death” (Wärmetod) will have come.
If Clausius were right, however, this heat-death, we may object, should
already have occurred in the infinitely long space of time that the
universe has been in existence. Or we might argue that the world has
not yet been in existence sufficiently long, but that, anyhow, it had a
beginning. That would contradict the first part of the law of Clausius,
that the energy of the universe is constant; for in that case all the
energy would have originated in the moment of creation. That is quite
inconceivable, and we must hence look for conditions for which the
entropy law of Clausius does not hold.
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