Worlds in the making: The evolution of the universeArrhenius, Svante
Science
Worlds in the making: The evolution of the universe
Arrhenius, Svante
Cosmogony
The famous Scotch physicist Clerk-Maxwell has conceived of such a case.
Imagine a vessel which is divided by a partition into two halves, both
charged with a gas of perfectly uniform temperature. Let the partition
be provided with a number of small holes which would not allow more
than one gas molecule to pass at a time. In each hole Maxwell places a
small, intelligent being (one of his “demons”), which directs all the
molecules which enter into the hole, and which have a greater velocity
than the mean velocity of all the molecules, to the one side, and which
sends to the other side all the molecules of a smaller velocity than
the average.[19] All the undesirable molecules the demon bars by means
of a little flap. In this way all the molecules of a velocity greater
than the average may be collected in the one compartment, and all the
molecules of a lesser velocity in the other compartment. In other
words, heat—for heat consists in the movements of molecules—will pass
from the one constantly cooling side to the other, which is constantly
raising its temperature, and which must therefore become warmer than
the former.
[Footnote 19: The kinetic theory of gases imagines all the
molecules of a gas to be in constant motion. The internal
pressure of the gas depends upon the mean velocity of the
particles; but some particles will move at a greater, and some
at a smaller velocity than the average.—H.B.]
In this instance heat would therefore pass from a colder to a warmer
body, and the entropy would diminish.
Public-domain text, read in full here on John Shaqi.
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