Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity — John Shaqi
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
Science
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
It was possible to suppose, then, that the main structure of the atom
was positively charged and generally immovable, and that there were also
present light electrons, which could easily be detached. Thomson had
suggested, as early as 1898, that the atom was a ball of matter carrying
a positive charge and that individual electrons were stuck throughout
its substance, like raisins in pound cake.
If something like the Thomson view were correct then the number of
electrons, each with one unit of negative electricity, would depend on
the total size of the positive charge carried by the atom. If the charge
were +5, there would have to be 5 electrons present to balance that. The
total charge would then be 0 and the atom as a whole would be
electrically neutral.
If, in such a case, an electron were removed, the atomic charge of +5
would be balanced by only 4 electrons with a total charge of -4. In that
case, the net charge of the atom as a whole would be +1. On the other
hand, if an extra electron were forced onto the atom, the charge of +5
would be balanced by 6 electrons with a total charge of -6, and the net
charge of the atom as a whole would be -1.
Such electrically charged atoms were called “ions” and their existence
had been suspected since Faraday’s day. Faraday had known that atoms had
to travel through a solution under the influence of an electric field to
account for the way in which metals and gases appeared at the cathode
and anode. It was he who first used the term, ion, from a Greek word
meaning “traveller”. The word had been suggested to him by the English
scholar, William Whewell (1794-1866). In 1884 the Swedish chemist Svante
August Arrhenius (1859-1927) had first worked out a detailed theory
based on the suggestion that these ions were atoms or groups of atoms
that carried an electric charge.
[Illustration: _Svante A. Arrhenius_]
By the close of the 19th century, then, Arrhenius’s suggestion seemed
correct. There were positive ions made up of atoms or groups of atoms,
from which one or more of the electrons within the atoms had been
removed. There were negative ions made up of single atoms or of groups
of atoms, to which one or more extra electrons had been added.
[Illustration: ]
Neutral atom
Each unit of positive charge is balanced by a unit of negative
charge
In this case, total charge = +2 -2 = 0
Ionized atom:
If an electron is removed, the balance is destroyed
In this case, total charge = +2 -1 = +1
Although Thomson’s model of the atom explained the existence of ions and
the fact that atoms could give off electrons or absorb them, it was not
satisfactory in all ways. Further investigations yielded results not
compatible with the raisins-in-the-pound-cake notion.
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