Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
Science
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
The answer came through a line of research that began with the English
physicist Charles Glover Barkla (1877-1944). In 1911 he noted that when
X rays passed through atoms, some were absorbed and some bounced back.
Those that bounced back had a certain ability to penetrate other matter.
When the X rays struck atoms of high atomic weight, the X rays that
bounced back were particularly penetrating. In fact, each different type
of atom seemed associated with reflected X rays of a particular
penetrating power, so Barkla called these “characteristic X rays”.
In 1913 another English physicist, Henry Gwyn-Jeffreys Moseley
(1887-1915), went into the matter more thoroughly. He measured the exact
wavelength of the characteristic X rays by reflecting them from certain
crystals. In crystals, atoms are arranged in regular order and at known
distances from each other. X rays reflecting from (or more accurately,
diffracting from) crystals are bent out of their path by the rows of
atoms. The longer their waves, the more they are bent. From the degree
of bending the wavelength of the waves can be determined.
[Illustration: _Charles Glover Barkla_]
[Illustration: _Henry Gwyn-Jeffreys Moseley_]
Moseley found that the greater the atomic weight of an atom, the shorter
the waves of the characteristic X rays associated with it and the more
penetrating those X rays were. There was such a close connection, in
fact, that Moseley could arrange the elements in order according to the
wavelength of the characteristic X rays.
For some 40 years prior to this, the elements had been listed in order
of atomic weight. This was useful especially since the Russian chemist
Dmitri I. Mendeléev (1834-1907) had arranged them in a “periodic table”
based on the atomic weight order in such a way that elements of similar
properties were grouped together. The elements in this table were
sometimes numbered consecutively (“atomic number”) but this was
inconvenient since, when new elements were discovered, the list of
atomic numbers might have to be reorganized.
[Illustration: _Dmitri Mendeléev and Bohuslav Brauner in Prague in 1900.
Brauner was a professor of chemistry at the Bohemian University in
Prague._]
The Danish physicist Niels Bohr (1885-1962) had just advanced a theory
of atomic structure that made it reasonable to suppose that the
wavelength of the characteristic X rays depended on the size of the
nuclear charge of the atoms making up a particular element. Moseley
therefore suggested that these X rays be used to determine the size of
the positive charge on its nucleus. The atomic number could then be set
equal to that charge and be made independent of new discoveries of
elements.
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