Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
Science
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
The various atoms formed in these three radioactive series were not all
different in every way. When the uranium atom gives off an alpha
particle, it forms an atom originally called “uranium X₁”. On close
investigation, it turned out that this uranium X₁ had the chemical
properties of thorium. Uranium X₁, had, however, radioactive properties
different from ordinary thorium.
Uranium X₁ broke down so rapidly, giving off beta particles as it did
so, that half of any given quantity would have broken down in 24 days.
Another way of saying this (which was introduced by Rutherford) was that
the “half-life” of uranium X₁, is 24 days. Ordinary thorium, however,
gives off alpha particles, not beta particles, and does so at such a
slow rate, that its half-life is 14 billion years!
Uranium X₁, and ordinary thorium were in the same place in the list of
elements by chemical standards, and yet there was clearly something
different about the two.
Here is another case. In 1913 the British chemist Alexander Fleck
(1889- ) studied “radium B” and “radium D”, the names given to two
different kinds of atoms in the uranium radioactive series. He also
studied “thorium B” in the thorium radioactive series and “actinium B”
in the actinium radioactive series. All four are chemically the same as
ordinary lead; all four are in the same place in the list of elements.
Yet each is different from the radioactive standpoint. Though all give
off beta particles, radium B has a half-life of 27 minutes, radium D one
of 19 years, thorium B one of 11 hours, and actinium B one of 36
minutes.
In 1913 Soddy called atoms that were in the same place in the list of
elements, but which had different radioactive properties, “isotopes”,
from Greek words meaning “same place”.
At first, it seemed that the only difference between isotopes might be
in their radioactive properties and that only radioactive atoms were
involved. Quickly that proved not to be so.
It proved that it was possible to have several forms of the same element
that were all different even though none of them were radioactive. The
uranium series, the thorium series, and the actinium series all ended in
lead. In each case the lead formed was stable (not radioactive). Were
the lead atoms identical in every case? Soddy had worked out the way in
which atomic weights altered every time an alpha particle or a beta
particle was given off by an atom. Working through the three radioactive
series he decided that the lead atoms had different atomic weights in
each case.
The uranium series ought to end with lead atoms that had an atomic
weight of 206. The thorium series ought to end in lead atoms with an
atomic weight of 208 and the actinium series in lead atoms with an
atomic weight of 207.
Public-domain text, read in full here on John Shaqi.
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