Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; ElectricityAsimov, Isaac
Science
Worlds Within Worlds: The Story of Nuclear Energy, Volume 1 (of 3): Atomic Weights; Energy; Electricity
Asimov, Isaac
Nuclear energy -- Popular works
The neon ions ended on a photographic plate, which was darkened at the
point of landing. There were two regions of darkening, because there
were neon ions of two different masses that curved in two different
degrees and ended in two different places. Thomson showed, from the
amount of curving, that there was a neon isotope with an atomic weight
of 20 and one with an atomic weight of 22—²⁰Ne and ²²Ne.
What’s more, from the intensity of darkening, it could be seen that
ordinary neon was made up of atoms that were roughly 90% ²⁰Ne and 10%
²²Ne. The overall atomic weight of neon, 20.2, was the average atomic
weight of these 2 isotopes.
Thomson’s instrument was the first one capable of separating isotopes
and such instruments came to be called “mass spectrometers”. The first
to use the name was the English physicist Francis William Aston
(1877-1945), who built the first efficient instrument of this type in
1919.
He used it to study as many elements as he could. He and those who
followed him located many isotopes and determined the frequency of their
occurrence with considerable precision. It turned out, for instance,
that neon is actually 90.9% ²⁰Ne, and 8.8% ²²Ne. Very small quantities
of still a third isotope, ²¹Ne, are also present, making up 0.3%.
As for ordinary lead in nonradioactive rocks, it is made up of 23.6%
²⁰⁶Pb, 22.6% ²⁰⁷Pb, and 52.3% ²⁰⁸Pb. There is still a fourth isotope,
²⁰⁴Pb, which makes up the remaining 1.5% and which is not the product of
any radioactive series at all.
The isotopes always have atomic weights that are close to, but not
quite, whole numbers. Any atomic weight of an element that departs
appreciably from an integer does so only because it is an average of
different isotopes. For instance, the atomic weight of chlorine
(chemical symbol Cl) is 35.5, but this is because it is made up of a
mixture of 2 isotopes. About one quarter of chlorine’s atoms are ³⁷Cl
and about three-quarters are ³⁵Cl.
[Illustration: _Francis W. Aston_]
[Illustration: _Mass spectrograph as used by Thomson and Aston to
measure the atomic weight of neon._]
To avoid confusion, the average mass of the isotopes that make up a
particular element is still called the atomic weight of that element.
The integer closest to the mass of the individual isotope is spoken of
as the “mass number” of that isotope. Thus, chlorine is made up of
isotopes with mass numbers 35 and 37, but the atomic weight of chlorine
as it is found in nature is 35.5 (or, to be more accurate, 35.453).
In the same way, ordinary lead is made up of isotopes with mass numbers
204, 206, 207, and 208, and its atomic weight is 207.19; neon is made up
of isotopes with mass numbers 20, 21, and 22, and its atomic weight is
20.183, and so on.
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