_The Scientific American_ (September, 1924) published an abstract of
a paper read before the _Deutschen Bunsen-Gesellschaft_, in which
Dr. D. Coster showed that “the relations between the X-ray spectra of
the different elements are so simple that, in some respects, they are
more useful for purposes of chemical analysis than ordinary luminous
spectra. An important advantage is the fact that the X-ray spectrum
of an element is quite independent of the nature of the compound
containing it. It is easy to detect the presence in a mixture of
which not more than one milligram is available. Certain precautions
are necessary in examining the X-ray spectra; although the number of
lines for each element is comparatively limited, recent observations
have shown the existence of a number of weaker lines; in addition to
this, with the high voltages now generally used, not only the spectrum
of the first order, but also those of higher orders appear. Slight
impurities in the material of the anticathode, and in the subject
under examination, also give their lines, so that there are often
various possibilities to be considered before a given line can be
explained. Not only the wave length, but also the typical appearance
of the suspected lines must be considered, as well as their relative
intensity. By measuring photometrically the intensity of the spectral
lines it is possible, in some cases, to obtain a quantitative estimate
of the amount of an element present in a mixture.”
Another method of rapid analysis of material in the laboratory by
the use of X-rays in a much shorter time than that required by the
older chemical methods is that devised by Professor Urbain, of the
Minero-Chemical Laboratory at the Sorbonne, with the assistance of
Eugene Delaunay. Mr. Delaunay, who did the actual work of testing the
new X-ray method, says there is no risk of error.
By employment of X-rays the scientist is now able to ascertain the
arrangement of the atoms and molecules within the crystal “network”
(structure—or “space lattice” of the crystal).[1] The results are
obtained from the study of the reflection and refraction of the rays by
the crystals, or, more precisely, the successive rows of molecules in
the crystal. These act toward the extremely short X-rays in the same
way as a grating spectroscope does to ordinary light-rays.
Public-domain text, read in full here on John Shaqi.
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