The electron, its isolation and measurement and the determination of some of its properties
John Stuart Mill · en
I have already indicated that as soon as is known it becomes
possible to find with the same precision which has been attained in its
determination the exact number of molecules in a given weight of any
substance, the absolute weight of any atom or molecule, the average
kinetic energy of agitation of an atom or molecule at any temperature,
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and a considerable number of other important molecular and radioactive
constants. In addition, it has recently been found that practically all
of the important radiation constants like the wave-lengths of X-rays,
Planck’s , the Stefan-Boltzmann constant , the Wien
constant , etc., depend for their most reliable evaluation
upon the value of . In a word, is increasingly coming to be
regarded, not only as the most fundamental of physical or chemical
constants, but also the one of most supreme importance for the solution
of the numerical problems of modern physics. It seemed worth while,
therefore, to drive the method herewith developed for its determination
to the limit of its possible precision. Accordingly, in 1914 I built a
new condenser having surfaces which were polished optically and made
flat to within two wave-lengths of sodium light. These were 22 cm. in
diameter and were separated by 3 pieces of echelon plates, 14.9174
mm. thick, and all having optically perfect plane-parallel surfaces.
The dimensions of the condenser, therefore, no longer introduced
an uncertainty of more than about 1 part in 10,000. The volts were
determined after each reading in terms of a Weston standard cell
and are uncertain by no more than 1 part in 3,000. The times were
obtained from an exceptionally fine printing chronograph built by
William Gaertner & Co. It is controlled by a standard astronomical
clock and prints directly the time to hundredths of a second. All the
other elements of the problem were looked to with a care which was the
outgrowth of five years of experience with measurements of this kind.
The present form of the apparatus is shown in diagram in Fig. 8, and in
Fig. 9 is shown a photograph taken before the enclosing oil tank had
been added.
Fig. 8—, atomizer through which the oil spray is blown into the
cylindrical vessel . oil tank to keep the temperature
constant. and , circular brass plates, electric field
produced by throwing om 10.009-volt battery . Light from arc lamp
after heat rays are removed by passage through and ,
enters chamber through glass window and illuminates droplet
between plates and through the pinhole in . Additional
ions are produced above by X-rays from the bulb .
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Fig. 9
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