A handbook of laboratory glass-blowingBolas, Bernard D. (Bernard Dell)
Science
A handbook of laboratory glass-blowing
Bolas, Bernard D. (Bernard Dell)
Glass blowing and working
There are three kinds of glass rod and tubing which are easily
obtainable; these are soda-glass, which is that usually supplied by
chemical apparatus dealers when no particular glass is specified;
combustion-glass, which is supplied for work requiring a glass that does
not so easily soften or fuse as soda-glass; and lead-glass, which is
less common. There are also resistance-glass, made for use where very
slight solubility in water or other solutions is desirable, and a number
of other special glasses; but of these soda-glass, combustion-glass,
lead-glass, and resistance-glass are the most important to the
glass-blower whose work is connected with laboratory needs.
_Soda-Glass._--Consists chiefly of sodium silicate, but contains
smaller quantities of aluminum silicate, and often of calcium silicate;
there may also be traces of several other compounds.
The ordinary soda-glass tubing melts easily in the blowpipe flame, it
has not a long intermediate or viscous stage during fusion, but becomes
highly fluid rather suddenly; it does not blacken in the reducing flame.
Bad soda-glass or that which has been kept for many years, tends to
devitrify when worked. That is to say the glass becomes more or less
crystalline and infusible while it is in the flame; and in this case it
is often impossible to do good work with that particular sample of
glass; although the devitrification may sometimes be remedied by heating
the devitrified glass to a higher temperature. The presence of aluminum
compounds appears to have some influence on the tendency of the glass to
resist devitrification. Soda-glass, as a rule, is more liable to crack
by sudden heating than lead-glass, and articles made from soda-glass
often tend to crack spontaneously if badly made or, in the case of
heavier and thicker articles, if insufficiently annealed.
_Combustion-Glass._--Is usually a glass containing more calcium silicate
and potassium silicate than the ordinary "soft" soda-glass. It is much
less fusible than ordinary soda-glass, and passes through a longer
intermediate or viscous stage when heated. Such a glass is not very
suitable for use with the blowpipe owing to the difficulty experienced
in obtaining a sufficiently high temperature. If, however, a certain
amount of oxygen is mixed with the air used in producing the blowpipe
flame this difficulty is minimised.
_Resistance-Glass._--May contain zinc, magnesium, and other substances.
As a rule it is harder than ordinary soda-glass, and less suitable for
working in the blowpipe flame. It should have very little tendency to
dissolve in water, and hence is used when traces of alkali or silicates
would prove injurious in the solutions for which the glass vessels are
to be used.
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