A handbook of laboratory glass-blowingBolas, Bernard D. (Bernard Dell)
Science
A handbook of laboratory glass-blowing
Bolas, Bernard D. (Bernard Dell)
Glass blowing and working
_Lead-Glass._--This, or "flint" glass as it is often called from the
fact that silica in the form of crushed and calcined flint was often
used in making the English lead-glasses, contains a considerable
proportion of lead silicate. Such a glass has, usually, a particularly
bright appearance, a high refractive index, and is specially suitable
for the production of the heavy "cut-glass" ware.
Lead-glass tubing is easy to work in the blowpipe flame, melts easily,
but does not become fluid quite so suddenly as most soda-glasses;
articles made from it are remarkably stable and free from tendency to
spontaneous cracking, although, as is essential for all the heavy or
"glass-house" work, the massive articles need annealing in the oven.
The two chief disadvantages of lead-glass for laboratory work are that
it is blackened by the reducing gases if held too near to the blue cone
of the blowpipe flame, and that it is rather easily attacked by chemical
reagents; thus ammonium sulphide will cause blackening.
The effect of the reducing flame on lead is not altogether a
disadvantage, however; because a little care in adjusting the blowpipe
and a little care in holding the glass in the right position will enable
the student to work lead-glass without producing the faintest trace of
blackening. This, in addition to being a valuable exercise in
manipulation, will teach him to keep his blowpipe in good order, and
prove a useful aid in his early efforts to judge as to the condition of
the flame. It prevents discouragement if the student does his
preliminary work with the soda-glass, but he should certainly make
experiments with lead-glass as soon as he has acquired reasonable
dexterity with soda-glass.
_Annealing._--Annealing is a process by which any condition of strain
which has been set up in a glass article, either by rapid cooling of one
part while another part still remains hot, or by the application of
mechanical stress after cooling is relieved. Annealing is carried out by
subjecting the article to a temperature just below the softening point
of the glass, maintaining that temperature until the whole article has
become heated through the thicker part, and then reducing the
temperature very gradually; thus avoiding any marked cooling of the
thinner and outer parts first.
For thin glass apparatus of the lamp-blown or blowpipe-made variety in
which there are no marked difference of thickness, such as joins on
tubes, ordinary seals, bulbs, etc., there is little need for annealing;
and even those having rather marked changes of thickness, such as
filter pumps, can be annealed sufficiently by taking care that the last
step in making is heating to just below visible redness in the blowpipe
flame and then rotating in a sooty gas flame until covered with a
deposit of carbon. The article should then be allowed to cool in a place
free from draughts and where the hot glass will not come in contact with
anything.
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