A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
The universal fame of the great Swedish authority served to give general
currency to his symbols and atomic weights, and the new point of view
thus developed led presently to two important discoveries which removed
the last lingering doubts as to the validity of the atomic theory. In
1819 two French physicists, Dulong and Petit, while experimenting with
heat, discovered that the specific heats of solids (that is to say, the
amount of heat required to raise the temperature of a given mass to a
given degree) vary inversely as their atomic weights. In the same year
Eilhard Mitscherlich, a German investigator, observed that compounds
having the same number of atoms to the molecule are disposed to form the
same angles of crystallization--a property which he called isomorphism.
Here, then, were two utterly novel and independent sets of empirical
facts which harmonize strangely with the supposition that substances are
composed of chemical atoms of a determinate weight. This surely could
not be coincidence--it tells of law. And so as soon as the claims of
Dulong and Petit and of Mitscherlich had been substantiated by other
observers, the laws of the specific heat of atoms, and of isomorphism,
took their place as new levers of chemical science. With the aid of
these new tools an impregnable breastwork of facts was soon piled about
the atomic theory. And John Dalton, the author of that theory, plain,
provincial Quaker, working on to the end in semi-retirement, became
known to all the world and for all time as a master of masters.
HUMPHRY DAVY AND ELECTRO-CHEMISTRY
During those early years of the nineteenth century, when Dalton was
grinding away at chemical fact and theory in his obscure Manchester
laboratory, another Englishman held the attention of the chemical world
with a series of the most brilliant and widely heralded researches. This
was Humphry Davy, a young man who had conic to London in 1801, at the
instance of Count Rumford, to assume the chair of chemical philosophy in
the Royal Institution, which the famous American had just founded.
Here, under Davy's direction, the largest voltaic battery yet
constructed had been put in operation, and with its aid the brilliant
young experimenter was expected almost to perform miracles. And indeed
he scarcely disappointed the expectation, for with the aid of his
battery he transformed so familiar a substance as common potash into
a metal which was not only so light that it floated on water, but
possessed the seemingly miraculous property of bursting into flames as
soon as it came in contact with that fire-quenching liquid. If this
were not a miracle, it had for the popular eye all the appearance of the
miraculous.
Public-domain text, read in full here on John Shaqi.
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