A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
What Davy really had done was to decompose the potash, which hitherto
had been supposed to be elementary, liberating its oxygen, and thus
isolating its metallic base, which he named potassium. The same
thing was done with soda, and the closely similar metal sodium was
discovered--metals of a unique type, possessed of a strange avidity for
oxygen, and capable of seizing on it even when it is bound up in the
molecules of water. Considered as mere curiosities, these discoveries
were interesting, but aside from that they were of great theoretical
importance, because they showed the compound nature of some familiar
chemicals that had been regarded as elements. Several other elementary
earths met the same fate when subjected to the electrical influence; the
metals barium, calcium, and strontium being thus discovered. Thereafter
Davy always referred to the supposed elementary substances (including
oxygen, hydrogen, and the rest) as "unde-compounded" bodies. These
resist all present efforts to decompose them, but how can one know what
might not happen were they subjected to an influence, perhaps some day
to be discovered, which exceeds the battery in power as the battery
exceeds the blowpipe?
Another and even more important theoretical result that flowed from
Davy's experiments during this first decade of the century was the
proof that no elementary substances other than hydrogen and oxygen are
produced when pure water is decomposed by the electric current. It was
early noticed by Davy and others that when a strong current is passed
through water, alkalies appear at one pole of the battery and acids at
the other, and this though the water used were absolutely pure. This
seemingly told of the creation of elements--a transmutation but one step
removed from the creation of matter itself--under the influence of the
new "force." It was one of Davy's greatest triumphs to prove, in the
series of experiments recorded in his famous Bakerian lecture of 1806,
that the alleged creation of elements did not take place, the substances
found at the poles of the battery having been dissolved from the walls
of the vessels in which the water experimented upon had been placed.
Thus the same implement which had served to give a certain philosophical
warrant to the fading dreams of alchemy banished those dreams
peremptorily from the domain of present science.
Public-domain text, read in full here on John Shaqi.
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