A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
According to the phlogistic theory, the part remaining after a substance
was burned was simply the original substance deprived of phlogiston. To
restore the original combustible substance, it was necessary to heat the
residue of the combustion with something that burned easily, so that the
freed phlogiston might again combine with the ashes. This was explained
by the supposition that the more combustible a substance was the more
phlogiston it contained, and since free phlogiston sought always to
combine with some suitable substance, it was only necessary to mix the
phlogisticating agents, such as charcoal, phosphorus, oils, fats, etc.,
with the ashes of the original substance, and heat the mixture, the
phlogiston thus freed uniting at once with the ashes. This theory fitted
very nicely as applied to the calcined lead revivified by the grains of
wheat, although with some other products of calcination it did not seem
to apply at all.
It will be seen from this that the phlogistic theory was a step towards
chemistry and away from alchemy. It led away from the idea of a "spirit"
in metals that could not be seen, felt, or appreciated by any of the
senses, and substituted for it a principle which, although a falsely
conceived one, was still much more tangible than the "spirit," since it
could be seen and felt as free phlogiston and weighed and measured as
combined phlogiston. The definiteness of the statement that a metal,
for example, was composed of phlogiston and an element was much less
enigmatic, even if wrong, than the statement of the alchemist that
"metals are produced by the spiritual action of the three principles,
salt, mercury, sulphur"--particularly when it is explained that salt,
mercury, and sulphur were really not what their names implied, and that
there was no universally accepted belief as to what they really were.
The metals, which are now regarded as elementary bodies, were considered
compounds by the phlogistians, and they believed that the calcining of
a metal was a process of simplification. They noted, however, that the
remains of calcination weighed more than the original product, and the
natural inference from this would be that the metal must have taken in
some substance rather than have given off anything. But the phlogistians
had not learned the all-important significance of weights, and their
explanation of variation in weight was either that such gain or loss
was an unimportant "accident" at best, or that phlogiston, being light,
tended to lighten any substance containing it, so that driving it out of
the metal by calcination naturally left the residue heavier.
Public-domain text, read in full here on John Shaqi.
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