A History of Science — Volume 4Williams, Henry Smith
History
A History of Science — Volume 4
Williams, Henry Smith
Science -- History
Although this explanation of the composition of the air is most crude,
it had the effect of directing attention to the fact that the
atmosphere is not "mere nothingness," but a "something" with a
definite composition, and this served as a good foundation for future
investigations. To be sure, Boyle was neither the first nor the only
chemist who had suspected that the air was a mixture of gases, and not
a simple one, and that only certain of these gases take part in the
process of calcination. Jean Rey, a French physician, and John Mayow, an
Englishman, had preformed experiments which showed conclusively that the
air was not a simple substance; but Boyle's work was better known, and
in its effect probably more important. But with all Boyle's explanations
of the composition of air, he still believed that there was an
inexplicable something, a "vital substance," which he was unable to
fathom, and which later became the basis of Stahl's phlogiston theory.
Commenting on this mysterious substance, Boyle says: "The difficulty
we find in keeping flame and fire alive, though but for a little time,
without air, renders it suspicious that there be dispersed through the
rest of the atmosphere some odd substance, either of a solar, astral, or
other foreign nature; on account of which the air is so necessary to the
substance of flame!" It was this idea that attracted the attention
of George Ernst Stahl (1660-1734), a professor of medicine in the
University of Halle, who later founded his new theory upon it. Stahl's
theory was a development of an earlier chemist, Johann Joachim Becker
(1635-1682), in whose footsteps he followed and whose experiments he
carried further.
In many experiments Stahl had been struck with the fact that certain
substances, while differing widely, from one another in many respects,
were alike in combustibility. From this he argued that all combustible
substances must contain a common principle, and this principle he named
phlogiston. This phlogiston he believed to be intimately associated in
combination with other substances in nature, and in that condition not
perceivable by the senses; but it was supposed to escape as a substance
burned, and become apparent to the senses as fire or flame. In other
words, phlogiston was something imprisoned in a combustible structure
(itself forming part of the structure), and only liberated when this
structure was destroyed. Fire, or flame, was FREE phlogiston, while the
imprisoned phlogiston was called COMBINED PHLOGISTON, or combined fire.
The peculiar quality of this strange substance was that it disliked
freedom and was always striving to conceal itself in some combustible
substance. Boyle's tentative suggestion that heat was simply motion was
apparently not accepted by Stahl, or perhaps it was unknown to him.
Public-domain text, read in full here on John Shaqi.
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