A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
But now another phase of the problem presents itself to the
experimenter. Oxygen has assumed the quiescent liquid state, to be
sure, but in so doing it has fallen below the temperature of its cooling
medium; hence it is now receiving from that medium more energy of
vibration than it gives, and unless this is prevented very soon its
particles will again have power to kick themselves apart and resume the
gaseous state. Something, then, must be done to insulate the liquefied
gas, else it will retain the liquid state for too short a time to be
much experimented with. How might such insulation be accomplished?
The most successful attack upon this important problem has been made by
Professor Dewar. He invented a receptacle for holding liquefied gases
which, while not fulfilling the ideal conditions referred to above, yet
accomplishes a very remarkable degree of heat insulation. In consists of
a glass vessel with double walls, the space between which is rendered
a vacuum of the highest practicable degree. This vacuum, containing
practically no particles of matter, cannot, of course, convey
heat-impulses to or from the matter in the receptacle with any degree
of rapidity. Thus one of the two possible means of heat transfer is shut
off and a degree of insulation afforded the liquefied substance. But
of course the other channel, ether radiation, remains. Even this may be
blocked to a large extent, however, by leaving a trace of mercury vapor
in the vacuum space, which will be deposited as a fine mirror on
the inner surface of the chamber. This mirror serves as an admirable
reflector of the heat-rays that traverse the vacuum, sending more
than half of them back again. So, by the combined action of vacuum and
mirror, the amount of heat that can penetrate to the interior of the
receptacle is reduced to about one-thirtieth of what would enter an
ordinary vessel. In other words, a quantity of liquefied gas which would
evaporate in one minute from an ordinary vessel will last half an hour
in one of Professor Dewar's best vacuum vessels. Thus in one of these
vessels a quantity of liquefied air, for example, can be kept for a
considerable time in an atmosphere at ordinary temperature, and will
only volatilize at the surface, like water under the same conditions,
though of course more rapidly; whereas the same liquid in an ordinary
vessel would boil briskly away, like water over a fire. Only, be it
remembered, the air in "boiling" is at a temperature of about one
hundred and eighty degrees below zero, so that it would instantly freeze
almost any substance placed into it. A portion of alcohol poured on its
surface will be changed quickly into a globule of ice, which will
rattle about the sides of the vessel like a marble. That is not what one
ordinarily thinks of as a "boiling" temperature.
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